Isomerizations of a Pt4 cluster revealed by spatiotemporal microscopic analysis

被引：28
|
作者：
Imaoka, Takane [1 ,2 ,3 ]
Toyonaga, Tetsuya [1 ]
Morita, Mari [2 ]
Haruta, Naoki [2 ]
Yamamoto, Kimihisa [1 ,2 ]
机构：
[1] Tokyo Inst Technol, Inst Innovat Res, Lab Chem & Life Sci CLS, Yokohama, Kanagawa 2268503, Japan
[2] Tokyo Inst Technol, ERATO JST Yamamoto Atom Hybrid Project, Yokohama, Kanagawa 2268503, Japan
[3] PRESTO JST, Kawaguchi, Saitama 3320012, Japan
来源：
CHEMICAL COMMUNICATIONS | 2019年 / 55卷 / 33期
关键词：
PLATINUM CLUSTERS; FLUXIONALITY; CATALYSIS; DYNAMICS; ATOMS;
D O I：
10.1039/c9cc00530g
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
We now report the first direct observation of the fluxional nature in which the four-atomic platinumcluster (Pt-4) randomly walks through several isomers. Time-lapse analysis by a Cs-corrected transmission electron microscope allowed us to acquire the atomic coordinates at a sub-angstrom space resolution and 0.2 s time resolution for each cluster isomer. The analysis revealed that the isomerization follows a simple first-order kinetic model.
引用
收藏
页码：4753 / 4756
页数：4
相关论文
共 50 条
  • [1] Ab initio study of oxygen reduction mechanism at Pt4 cluster
    Roudgar, Ata
    Eikerling, Michael
    van Santen, Rutger
    PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2010, 12 (03) : 614 - 620
  • [2] The significance of microscopic bladder neck involvement in radical prostatectomies: pT4 disease?
    Billis, A.
    Galvao, M.
    Bronner, M.
    Schultz, L.
    Ruano, T.
    Meirelles, L.
    Freitas, L. L. L.
    Magna, L. A.
    Ferreira, U.
    MODERN PATHOLOGY, 2008, 21 : 149A - 149A
  • [3] The significance of microscopic bladder neck invasion in radical prostatectomies: pT4 disease?
    Thais Ruano
    Luciana Meirelles
    Leandro L. Freitas
    Luis A. Magna
    Ubirajara Ferreira
    Athanase Billis
    International Urology and Nephrology, 2009, 41
  • [4] The significance of microscopic bladder neck invasion in radical prostatectomies: pT4 disease?
    Ruano, Thais
    Meirelles, Luciana
    Freitas, Leandro L.
    Magna, Luis A.
    Ferreira, Ubirajara
    Billis, Athanase
    INTERNATIONAL UROLOGY AND NEPHROLOGY, 2009, 41 (01) : 71 - 76
  • [5] The significance of microscopic bladder neck involvement in radical prostatectomies: pT4 disease?
    Billis, A.
    Galvao, M.
    Bronner, M.
    Schultz, L.
    Ruano, T.
    Meirelles, L.
    Freitas, L. L. L.
    Magna, L. A.
    Ferreira, U.
    LABORATORY INVESTIGATION, 2008, 88 : 149A - 149A
  • [6] STRUCTURE OF THE CLUSTER PT4(CO)5(PET3)4 IN SOLUTION
    YUDANOV, VF
    EREMENKO, NK
    MEDNIKOV, EG
    GUBIN, SP
    JOURNAL OF STRUCTURAL CHEMISTRY, 1984, 25 (01) : 41 - 44
  • [7] Theoretical study of the H2 reaction with a Pt4 (111) cluster
    Cruz, A
    Bertin, V
    Poulain, E
    Benitez, JI
    Castillo, S
    JOURNAL OF CHEMICAL PHYSICS, 2004, 120 (13): : 6222 - 6228
  • [8] The management of locally advanced (pT4) esophageal carcinomaTherapie des lokal fortgeschrittenen (pT4) Ösophaguskarzinoms
    T. Benhidjeb
    P. M. Schlag
    Acta Chirurgica Austriaca, 1999, 31 (1) : 5 - 8
  • [9] Methane activation by platinum cluster ions in the gas phase:: effects of cluster charge on the Pt4 tetramer
    Achatz, U
    Berg, C
    Joos, S
    Fox, BS
    Beyer, MK
    Niedner-Schatteburg, G
    Bondybey, VE
    CHEMICAL PHYSICS LETTERS, 2000, 320 (1-2) : 53 - 58
  • [10] Electronic excitations and optical spectra of Pt2 and Pt4 on Cu(001) modeled by a cluster
    Pal, George
    Lefkidis, Georgios
    Huebner, Wolfgang
    PHYSICA STATUS SOLIDI B-BASIC SOLID STATE PHYSICS, 2010, 247 (05): : 1109 - 1115
12345