Chiral Ionic Liquid/ESI-MS Methodology as an Efficient Tool for the Study of Transformations of Supported Organocatalysts

被引：7
|
作者：
Zlotin, S. G. [1 ]
Kuherenko, A. S. [1 ]
Maltsev, O. V. [1 ]
Chizhov, A. O. [1 ]
机构：
[1] Russian Acad Sci, ND Zelinsky Inst Organ Chem, Moscow 119991, Russia
来源：
TOPICS IN CATALYSIS | 2013年 / 56卷 / 11期
关键词：
Organocatalysis; Asymmetric synthesis; Supported organocatalysts; Ionic liquids; Mass-spectrometry; ASYMMETRIC MICHAEL REACTIONS; ELECTROSPRAY-IONIZATION MASS; ALDOL REACTIONS; IMINIUM CATALYSIS; MANNICH REACTIONS; ALDEHYDES; PROLINE; DERIVATIVES; THIOUREA; ACIDS;
D O I：
10.1007/s11244-013-0056-8
中图分类号：
O69 [应用化学];
学科分类号：
081704 ;
摘要：
An efficient approach to the study of deactivation pathways of chiral organocatalysts in asymmetric Michael reactions by modifying original catalysts with ionic-liquid fragments followed by the electrospray ionization mass spectrometry analysis of recovered catalyst samples has been proposed.
引用
收藏
页码：923 / 932
页数：10
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