Synthesis and luminescence properties of CaTiO3:Pr3+ phosphor from oxalate precursor

被引:7
作者
Chen, Rui [1 ]
Chen, Donghua [2 ]
机构
[1] Yunnan Normal Univ, Coll Chem & Chem Engn, Kunming 650500, Peoples R China
[2] South Cent Univ Nationalities, Coll Chem & Mat Sci, Hubei Key Lab Catalysis & Mat Sci, Wuhan 430074, Peoples R China
关键词
Ceramics; Perovskites; Luminescence; Thermal analysis; X-ray diffraction; RED LUMINESCENCE; HEAT-CAPACITY; CATIO3-PR3+; TEMPERATURE; IMPROVEMENT; PR3+;
D O I
10.1016/j.matlet.2013.03.139
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
CaTiO3:Pr3+ was synthesized from oxalate precursor [CaTiO(C2O4)(2)center dot 4H(2)O] (CTO) at 900 degrees C, in which Pr3+ ions were dispersed by room temperature grinding. The decomposition process of the oxalate precursor was analyzed by the thermogravimetry and differential thermogravimetry curve (TG-DTG). The crystallization and luminescence properties of CaTiO3:Pr3+ were tested by means of X-ray diffraction (XRD), luminescence spectrometer and brightness meter. The oxalate precursor has a characteristic of weak red afterglow after being excited by ultraviolet (UV) light at room temperature for 15 min. The result suggested that phosphor is typically synthesized for a doping level of 0.1 wt% at 900 degrees C for 6 h, which were regarded as the optimal synthesis conditions. (C) 2013 Elsevier B.V. All rights reserved.
引用
收藏
页码:1 / 3
页数:3
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