Optical temperature sensing through the upconversion luminescence from Ho3+/Yb3+ codoped CaWO4

被引:236
作者
Xu, Wei [1 ]
Zhao, Hua [2 ]
Li, Yaxin [3 ]
Zheng, Longjiang [3 ]
Zhang, Zhiguo [1 ,4 ]
Cao, Wenwu [1 ,5 ]
机构
[1] Harbin Inst Technol, Condensed Mater Sci & Technol Inst, Harbin 150001, Peoples R China
[2] Harbin Inst Technol, Sch Mat & Engn, Harbin 150001, Peoples R China
[3] Yanshan Univ, Inst Elect Engn, Qinhuangdao 066004, Peoples R China
[4] Harbin Inst Technol, Lab Sono & Phototheranost Technol, Harbin 150001, Peoples R China
[5] Penn State Univ, Mat Res Inst, University Pk, PA 16802 USA
关键词
Upconversion; Ho3+ ions; Blue emissions; Temperature sensor; THERMOMETRY; EMISSION; EFFICIENCY;
D O I
10.1016/j.snb.2013.07.094
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
Under 980 nm diode laser excitation, efficient upconversion emissions from the Ho3+/Yb3+ codoped CaWO4 phosphor were obtained. The upconversion quantum efficiency was evaluated to be about 3.3% when the power density of the excitation laser was 47 W/cm(2). Additionally, temperature dependent blue emissions from the F-5(2,3)/K-3(8) and (5)G(6)/F-5(1) states of Ho3+ ions were studied in the range of 303-923 K. The result demonstrated that using the ratio between the blue luminescence intensities of Ho3+ ions, the sensitivity and the accuracy for optical thermometry achieved here are superior to the previously reported Er3+ green fluorescence based optical temperature sensors. (C) 2013 Elsevier B.V. All rights reserved.
引用
收藏
页码:1096 / 1100
页数:5
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