Shaping the cavity of calix[4]arene using transition metals and binding alkali-metal cations inside the cavity: The relevance of the alkali-metal cation-arene interaction

被引：50
|
作者：
ZanottiGerosa, A
Solari, E
Giannini, L
Floriani, C
ChiesiVilla, A
Rizzoli, C
机构：
[1] UNIV LAUSANNE,BCH,INST CHIM MINERALE & ANALYT,CH-1015 LAUSANNE,SWITZERLAND
[2] UNIV PARMA,DIPARTIMENTO CHIM,I-43100 PARMA,ITALY
来源：
CHEMICAL COMMUNICATIONS | 1997年 / 02期
关键词：
D O I：
10.1039/a606826j
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Transition metals can be used for shaping and electronically enriching the calix[4]arene cavity; in this approach, the pi-basic cavities can be adapted to alkali-metal cation complexation in a very hydrophobic environment and these cations can even be transferred into aliphatic hydrocarbons; the eta(6)-arene-alkali-metal cation interaction is structurally elucidated.
引用
收藏
页码：183 / 184
页数：2
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