Deacidification of Pistacia chinensis Oil as a Promising Non-Edible Feedstock for Biodiesel Production in China

被引:17
作者
Qin, Shenjun [1 ,2 ]
Sun, Yuzhuang [1 ]
Shi, Changlin [1 ]
He, Leqin [1 ]
Meng, Yuan [1 ]
Ren, Xiaohui [1 ]
机构
[1] Hebei Univ Engn, Key Lab Resource Explorat Res Hebei Prov, Handan 056038, Hebei, Peoples R China
[2] China Univ Min & Technol, State Key Lab Coal Resources & Safe Min, Beijing 100008, Peoples R China
基金
中国国家自然科学基金;
关键词
biodiesel; Pistacia chinensis seed oil; deacidification; transesterification; ALKALI-CATALYZED TRANSESTERIFICATION; SEED OIL; ETHANOLYSIS;
D O I
10.3390/en5082759
中图分类号
TE [石油、天然气工业]; TK [能源与动力工程];
学科分类号
0807 ; 0820 ;
摘要
Pistacia chinensis seed oil is proposed as a promising non-edible feedstock for biodiesel production. Different extraction methods were tested and compared to obtain crude oil from the seed of Pistacia chinensis, along with various deacidification measures of refined oil. The biodiesel was produced through catalysis of sodium hydroxide (NaOH) and potassium hydroxide (KOH). The results showed that the acid value of Pistacia chinensis oil was successfully reduced to 0.23 mg KOH/g when it was extracted using ethanol. Consequently, the biodiesel product gave a high yield beyond 96.0%. The transesterification catalysed by KOH was also more complete. Fourier transform infrared (FTIR) spectroscopy was used to monitor the transesterification reaction. Analyses by gas chromatography-mass spectrometry (GC-MS) and gas chromatography with a flame ionisation detector (GC-FID) certified that the Pistacia chinensis biodiesel mainly consisted of C-18 fatty acid methyl esters (81.07%) with a high percentage of methyl oleate. Furthermore, the measured fuel properties of the biodiesel met the required standards for fuel use. In conclusion, the Pistacia chinensis biodiesel is a qualified and feasible substitute for fossil diesel.
引用
收藏
页码:2759 / 2770
页数:12
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