Anatase TiO2 Mesocrystals Enclosed by (001) and (101) Facets: Synergistic Effects between Ti3+ and Facets for Their Photocatalytic Performance

被引：67
作者：
Chen, Qifeng [1 ]
Ma, Wanhong [1 ]
Chen, Chuncheng [1 ]
Ji, Hongwei [1 ]
Zhao, Jincai [1 ]
机构：
[1] Chinese Acad Sci, Key Lab Photochem, Beijing Natl Lab Mol Sci, Inst Chem, Beijing 100190, Peoples R China
来源：
CHEMISTRY-A EUROPEAN JOURNAL | 2012年 / 18卷 / 40期
基金：
美国国家科学基金会;
关键词：
(101)/(001) facets; anatase; catalysis; mesocrystals; titanium; CRYSTALLIZATION; NANOPARTICLES; PERCENTAGE; CONVERSION; NANOSHEETS; MOLECULES; GROWTH; WATER; SIZE;
D O I：
10.1002/chem.201201178
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Let's facet it: TiO 2 mesocrystals (MCs; see figure) enclosed by (101) and (001) facets can be synthesized by a facile green approach and the ratio of (101)/(001) can be tuned simply by adjusting the solvothermal periods. The photocatalytic activity of TiO 2 MCs exposing high proportions of (101) facets possess higher photocatalytic activity than those with lower facets; this can be attributed to the synergistic effect of Ti 3+ and the (101)/(001) facet ratio. Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
引用
收藏
页码：12584 / 12589
页数：6
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