Anatase TiO2 Mesocrystals Enclosed by (001) and (101) Facets: Synergistic Effects between Ti3+ and Facets for Their Photocatalytic Performance

被引：67

作者：

Chen, Qifeng ^{[1
]}

Ma, Wanhong ^{[1
]}

Chen, Chuncheng ^{[1
]}

Ji, Hongwei ^{[1
]}

Zhao, Jincai ^{[1
]}

机构：

[1] Chinese Acad Sci, Key Lab Photochem, Beijing Natl Lab Mol Sci, Inst Chem, Beijing 100190, Peoples R China

来源：

CHEMISTRY-A EUROPEAN JOURNAL | 2012年 / 18卷 / 40期

基金：

美国国家科学基金会;

关键词：

(101)/(001) facets; anatase; catalysis; mesocrystals; titanium; CRYSTALLIZATION; NANOPARTICLES; PERCENTAGE; CONVERSION; NANOSHEETS; MOLECULES; GROWTH; WATER; SIZE;

D O I：

10.1002/chem.201201178

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Let's facet it: TiO 2 mesocrystals (MCs; see figure) enclosed by (101) and (001) facets can be synthesized by a facile green approach and the ratio of (101)/(001) can be tuned simply by adjusting the solvothermal periods. The photocatalytic activity of TiO 2 MCs exposing high proportions of (101) facets possess higher photocatalytic activity than those with lower facets; this can be attributed to the synergistic effect of Ti 3+ and the (101)/(001) facet ratio. Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：12584 / 12589

页数：6

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