Binary blends of Ziegler-Natta and metallocene catalyzed polyethylenes: Rheological properties

被引:0
作者
Rana, D [1 ]
Kim, HL [1 ]
Rhee, C [1 ]
Woo, T [1 ]
Park, SH [1 ]
Choe, A [1 ]
机构
[1] Inha Univ, Dept Chem Engn, Inst Polymer Sci & Engn, Inchon 402751, South Korea
来源
ANTEC '99: PLASTICS BRIDGING THE MILLENNIA, CONFERENCE PROCEEDINGS, VOLS I-III: VOL I: PROCESSING; VOL II: MATERIALS; VOL III: SPECIAL AREAS; | 1999年
关键词
rheology; morphology; polyethylene; Zieger-Natta and metallocene catalysts;
D O I
暂无
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
The rheological and morphological behaviors of three binary blends of polyethylenes regarding the melt index and density. one component made by Ziegler-Natta and the other by metallocene catalysts. have been investigated to elucidate miscibility and phase behavior. If the comonomer contents are similar, then the melt viscosity is weight average value, otherwise it shows different behavior: the FA+FM blend is miscible. but the RF+EN and RF+PL blends inform immiscible. The microtomed cutting surface indicates that all the blends are not homogenous regardless the density, melt index and cooling processes, and show banded spherulites.
引用
收藏
页码:3775 / 3779
页数:5
相关论文
共 26 条
[1]   THE RHEOLOGICAL BEHAVIOR OF HDPE LDPE BLENDS .4. INSTABILITY PHENOMENA IN CAPILLARY-FLOW [J].
ACIERNO, D ;
LAMANTIA, FP ;
CURTO, D .
POLYMER BULLETIN, 1984, 11 (03) :223-228
[2]   FLOW PROPERTIES OF LOW-DENSITY LINEAR LOW-DENSITY POLYETHYLENES [J].
ACIERNO, D ;
CURTO, D ;
LAMANTIA, FP ;
VALENZA, A .
POLYMER ENGINEERING AND SCIENCE, 1986, 26 (01) :28-33
[3]  
[Anonymous], 1989, POLYM ALLOYS BLENDS
[4]  
Cho K, 1997, J APPL POLYM SCI, V63, P1265, DOI 10.1002/(SICI)1097-4628(19970307)63:10<1265::AID-APP4>3.0.CO
[5]  
2-I
[6]  
CHO K, 1997, J IND ENG CHEM, V3, P147
[7]  
CHO K, IN PRESS POLYM ENG S
[8]  
Cogswell FN, 1981, POLYM MELT RHEOLOGY
[9]   Dispersion and absorption in dielectrics I. Alternating current characteristics [J].
Cole, KS ;
Cole, RH .
JOURNAL OF CHEMICAL PHYSICS, 1941, 9 (04) :341-351
[10]   BLENDS OF ISOTACTIC POLYPROPYLENE AND ETHYLENE-PROPYLENE RUBBERS - RHEOLOGY, MORPHOLOGY AND MECHANICS [J].
DANESI, S ;
PORTER, RS .
POLYMER, 1978, 19 (04) :448-457