Self-assembly of water cluster in Cu(II) complexes and magnetic property

被引：5

作者：

Wang Jun ^{[1
]}

Wu Wei-Ping

Lu Lu

Xie Bin

机构：

[1] Sichuan Univ Sci & Engn, Inst Functionalized Mat, Zigong 643000, Peoples R China

来源：

JOURNAL OF MOLECULAR STRUCTURE | 2013年 / 1036卷

关键词：

Coordination polymer; Crystal structure; Water cluster; Magnetism; METAL-ORGANIC FRAMEWORK; HEXAMERS; NEUTRON; CO(II); CHAIN; TAPES; FORM; ICE;

D O I：

10.1016/j.molstruc.2012.09.075

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Two new complexes, namely {[Cu-2(L)(3)(bipy)(2)]center dot 6.87H(2)O center dot NO3} (1) and {[Cu-2(L)(4)(H2O)(2)]center dot 2H(2)O} (2)(HL = 2-ethoxynicotinic acid and bipy = 2,2'-bipyridine) have been synthesized and structurally characterized by single-crystal diffraction analysis. In the dinuclear Cu(II) compounds of 1 and 2, hydrogen bond ineractions exist between host and guest molecules, resulting in interesting 3D supramolecular motifs. 10 T6(2)T8(2) water tape consisting of alternative cyclic water hexamers and octamers and dimmer water cluster are observed in complexes 1 and 2, respectively. Magnetic studies reveal the overall antiferromagnetic interaction between neighboring Cu(II) ions in compounds 1 and 2. (C) 2012 Elsevier B.V. All rights reserved.

引用

页码：174 / 179

页数：6

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