Effect of pore size on the performance of composite adsorbent

被引:36
作者
Bu, Xianbiao [1 ]
Wang, Lingbao [1 ]
Huang, Yuanfeng [1 ]
机构
[1] Chinese Acad Sci, Guangzhou Inst Energy Convers, Key Lab Renewable Energy & Gas Hydrate, Guangzhou 510640, Guangdong, Peoples R China
来源
ADSORPTION-JOURNAL OF THE INTERNATIONAL ADSORPTION SOCIETY | 2013年 / 19卷 / 05期
关键词
Refrigeration; Adsorption system; Composite; Adsorbent; Silica gel; Calcium chloride; SILICA-GEL; LITHIUM-CHLORIDE; WATER; SORPTION; ADSORPTION; SORBENT; CACL2;
D O I
10.1007/s10450-013-9513-8
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Three kinds of commercial silica gels with pore size of 2-3, 4-7 and 8-10 nm respectively are used for preparing composite adsorbents by soaking them into the aqueous solution of calcium chloride. The test result indicates that both the water uptake and adsorption rate of composite adsorbents prepared from 4-7 and 8-10 nm silica gels improve greatly compared to pure silica gels, but they do not for 2-3 nm silica gels. The silica gel with pore size of 2-3 nm is not suitable for preparing the composite adsorbent by impregnation method due to the pore blockage because of the small pore size. The SCP and COP of the adsorption chiller with sample SA50 are 128.3 Wkg(-1) and 0.27 respectively at the hot source temperature of 90 A degrees C, which are largely superior to that of SA0. Hence using the composite adsorbent instead of the pure silica gel can reduce the size of the adsorption chiller.
引用
收藏
页码:929 / 935
页数:7
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