The N-H Functional Group in Organometallic Catalysis

被引：339

作者：

Zhao, Baoguo ^{[1
]}

Han, Zhaobin ^{[2
]}

Ding, Kuiling ^{[2
]}

机构：

[1] Shanghai Normal Univ, Key Lab Resource Chem, Minist Educ, Shanghai Key Lab Rare Earth Funct Mat, Shanghai 200234, Peoples R China

[2] Chinese Acad Sci, Shanghai Inst Organ Chem, State Key Lab Organometall Chem, 345 Lingling Rd, Shanghai 200032, Peoples R China

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2013年 / 52卷 / 18期

关键词：

cooperative catalysis; NH effect; organometallic catalysis; self-assembly; supramolecular catalysis; ASYMMETRIC TRANSFER HYDROGENATION; HIGHLY ENANTIOSELECTIVE HYDROGENATION; LIGAND BIFUNCTIONAL CATALYSIS; RUTHENIUM HYDRIDE COMPLEXES; SUPRAMOLECULAR BIDENTATE LIGANDS; ACHIRAL BENZOPHENONE LIGAND; DYNAMIC KINETIC RESOLUTION; SUPPORTED CHIRAL CATALYSTS; TETHERED RU(II) CATALYSTS; ALPHA-HYDROXY KETONES;

D O I：

10.1002/anie.201204921

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The organometallic approach is one of the most active topics in catalysis. The application of NH functionality in organometallic catalysis has become an important and attractive concept in catalyst design. NH moieties in the modifiers of organometallic catalysts have been shown to have various beneficial functions in catalysis by molecular recognition through hydrogen bonding to give catalystsubstrate, ligandligand, ligandcatalyst, and catalystcatalyst interactions. This Review summarizes recent progress in the development of the organometallic catalysts based on the concept of cooperative catalysis by focusing on the NH moiety.

引用

页码：4744 / 4788

页数：45

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