The N-H Functional Group in Organometallic Catalysis

被引：334
作者：
Zhao, Baoguo [1 ]
Han, Zhaobin [2 ]
Ding, Kuiling [2 ]
机构：
[1] Shanghai Normal Univ, Key Lab Resource Chem, Minist Educ, Shanghai Key Lab Rare Earth Funct Mat, Shanghai 200234, Peoples R China
[2] Chinese Acad Sci, Shanghai Inst Organ Chem, State Key Lab Organometall Chem, 345 Lingling Rd, Shanghai 200032, Peoples R China
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2013年 / 52卷 / 18期
关键词：
cooperative catalysis; NH effect; organometallic catalysis; self-assembly; supramolecular catalysis; ASYMMETRIC TRANSFER HYDROGENATION; HIGHLY ENANTIOSELECTIVE HYDROGENATION; LIGAND BIFUNCTIONAL CATALYSIS; RUTHENIUM HYDRIDE COMPLEXES; SUPRAMOLECULAR BIDENTATE LIGANDS; ACHIRAL BENZOPHENONE LIGAND; DYNAMIC KINETIC RESOLUTION; SUPPORTED CHIRAL CATALYSTS; TETHERED RU(II) CATALYSTS; ALPHA-HYDROXY KETONES;
D O I：
10.1002/anie.201204921
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The organometallic approach is one of the most active topics in catalysis. The application of NH functionality in organometallic catalysis has become an important and attractive concept in catalyst design. NH moieties in the modifiers of organometallic catalysts have been shown to have various beneficial functions in catalysis by molecular recognition through hydrogen bonding to give catalystsubstrate, ligandligand, ligandcatalyst, and catalystcatalyst interactions. This Review summarizes recent progress in the development of the organometallic catalysts based on the concept of cooperative catalysis by focusing on the NH moiety.
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收藏
页码：4744 / 4788
页数：45
相关论文
共 489 条
  • [1] A succession of isomers of ruthenium dihydride complexes. Which one is the ketone hydrogenation catalyst?
    Abbel, R
    Abdur-Rashid, K
    Faatz, M
    Hadzovic, A
    Lough, AJ
    Morris, RH
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2005, 127 (06) : 1870 - 1882
  • [2] Synthesis of ruthenium hydride complexes containing beta-aminophosphine ligands derived from amino acids and their use in the H2-hydrogenation of ketones and imines
    Abdur-Rashid, K
    Guo, RW
    Lough, AJ
    Morris, RH
    Song, DT
    [J]. ADVANCED SYNTHESIS & CATALYSIS, 2005, 347 (04) : 571 - 579
  • [3] Mechanism of the hydrogenation of ketones catalyzed by trans-dihydrido(diamine)ruthenium(II) complexes
    Abdur-Rashid, K
    Clapham, SE
    Hadzovic, A
    Harvey, JN
    Lough, AJ
    Morris, RH
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2002, 124 (50) : 15104 - 15118
  • [4] RuHCl(diphosphine)(diamine): Catalyst precursors for the stereoselective hydrogenation of ketones and imines
    Abdur-Rashid, K
    Lough, AJ
    Morris, RH
    [J]. ORGANOMETALLICS, 2001, 20 (06) : 1047 - 1049
  • [5] Ruthenium dihydride RuH2(PPh3)2((R,R)-cyclohexyldiamine) and ruthenium monohydride RuHCl(PPh3)2((R,R)-cyclohexyldiamine):: Active catalyst and catalyst precursor for the hydrogenation of ketones and imines
    Abdur-Rashid, K
    Lough, AJ
    Morris, RH
    [J]. ORGANOMETALLICS, 2000, 19 (14) : 2655 - 2657
  • [6] Catalytic cycle for the asymmetric hydrogenation of prochiral ketones to chiral alcohols:: Direct hydride and proton transfer from chiral catalysts trans-Ru(H)2(diphosphine)(diamine) to ketones and direct addition of dihydrogen to the resulting hydridoamido complexes
    Abdur-Rashid, K
    Faatz, M
    Lough, AJ
    Morris, RH
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2001, 123 (30) : 7473 - 7474
  • [7] Abdur-Rashid K., 2009, Can. Pat. Appl., Patent No. [CA 2636947A1 20090106, 2636947]
  • [8] AIKAWA K, 2003, ANGEW CHEM, V115, P5613
  • [9] Catalyst-Controlled Diastereoselection in the Hydrogenation of Heterocycloalkyl Ketones
    Akashi, Masaya
    Arai, Noriyoshi
    Inoue, Tsutomu
    Ohkuma, Takeshi
    [J]. ADVANCED SYNTHESIS & CATALYSIS, 2011, 353 (11-12) : 1955 - 1960
  • [10] Aqueous asymmetric transfer hydrogenation using modular hydrophobic aminoalcohols
    Alza, Esther
    Bastero, Arnaia
    Jansat, Susanna
    Pericas, Miquel A.
    [J]. TETRAHEDRON-ASYMMETRY, 2008, 19 (03) : 374 - 378
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