Effect of effective areas on ionic conductivity in dense composite material composed of ionic and electronic conductors for solid oxide fuel cells

被引：2

作者：

Lee, Changbo ^{[1
]}

Bae, Joongmyeon ^{[1
]}

机构：

[1] Korea Adv Inst Sci & Technol, Dept Engn Mech, Taejon 305701, South Korea

来源：

SOLID STATE IONICS | 2008年 / 179卷 / 35-36期

关键词：

Ionic conductivity; Effective area; Oxygen reduction reaction; Composite material; Double-layered cathode;

D O I：

10.1016/j.ssi.2008.06.018

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

An ionic conductivity model for a dense composite material composed of an ionic conductor and an electronic conductor is investigated by considering effective areas. It was found that the effective areas of the oxygen reduction reaction at the material surface and the oxygen ion conduction through the material bulk are important factors for determining the ionic conductivity of the composites, although the oxygen reduction reaction per se is not a factor. The area-specific resistances (ASR) of single-layered and double-layered cathodes composed of La0.8Sr0.2MnO3 (LSM-82) and Zr0.85Y0.15O2 (YSZ) were measured and compared with the values predicted by the model. The degree of agreement between the measured and predicted ASR values validates the model for ionic conductivity in dense composite materials. Their impedance spectra were analyzed to support the results. (C) 2008 Elsevier B.V. All rights reserved.

引用

页码：2031 / 2036

页数：6

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