Fluorometric determination of ciprofloxacin using molecularly imprinted polymer and polystyrene microparticles doped with europium(III)(DBM)3phen

被引：27

作者：

Li, Zhuanying ^{[1
]}

Cui, Zhimeng ^{[1
]}

Tang, Yiwei ^{[1
,2
]}

Liu, Xiuying ^{[1
]}

Zhang, Xuemei ^{[3
]}

Liu, Bingxiang ^{[3
]}

Wang, Xianghong ^{[2
]}

Draz, Mohamed Shehata ^{[4
]}

Gao, Xue ^{[1
]}

机构：

[1] Bohai Univ, Coll Food Sci & Project Engn, Jinzhou 121013, Peoples R China

[2] Agr Univ Hebei, Coll Food Sci & Technol, Baoding 071001, Peoples R China

[3] Agr Univ Hebei, Coll Forestry, Baoding 071001, Peoples R China

[4] Harvard Med Sch, Brigham & Womens Hosp, Dept Med, Div Engn Med, Boston, MA 02139 USA

来源：

MICROCHIMICA ACTA | 2019年 / 186卷 / 06期

基金：

国家重点研发计划;

关键词：

Fluorometric determination; Polystyrene microparticles; Molecularly imprinted polymer; Europium(III)(DBM)(3)Phen; Luminophore; Ciprofloxacin; Fluorescent probe; Fish sample; Selective recognition; Quenching; PERFORMANCE LIQUID-CHROMATOGRAPHY; SOLID-PHASE EXTRACTION; QUANTUM DOTS; ULTRASENSITIVE DETECTION; COMPOSITE FILM; ACID; FLUORESCENCE; RECOGNITION; SAMPLES; CLENBUTEROL;

D O I：

10.1007/s00604-019-3448-z

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

The authors describe a microparticle-based system for the detection of the fluoroquinolone antibiotic ciprofloxacin. The method is using the tris(dibenzoylmethane)(1,10-phenanthroline)europium(III) luminophore in polystyrene microparticles along with a molecularly imprinted polymer (MIP) for ciprofloxacin. If ciprofloxacin is captured by the MIP, it quenches the fluorescence of the luminophores. Fluorescence drops linearly in the 0.5-100gL(-1) ciprofloxacin concentration range, and the detection limit is 92ngL(-1). The method was applied to the analysis of fish samples to assess the analytical performance of the probe. Recoveries ranged from 85.4 to 86.6%, and relative standard deviations between 2.1 and 3.9% (for n=5).

引用

页数：10

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