C-N Bond Formation Reaction Catalyzed by Organo-Rare-Earth Metal Amides

被引：12
作者：
Xiao, Yang [1 ]
Wang, Qianyu [1 ]
Zhao, Bei [1 ]
Yao, Yingming [1 ]
机构：
[1] Soochow Univ, Coll Chem Chem Engn & Mat Sci, Key Lab Organ Synth Jiangsu Prov, Suzhou 215123, Peoples R China
来源：
CHINESE JOURNAL OF ORGANIC CHEMISTRY | 2015年 / 35卷 / 08期
基金：
中国国家自然科学基金;
关键词：
rare-earth metal; amides; hydroamination; guanidination; amidation; amidination; INDENYL LIGAND SYNTHESIS; ALKALINE-EARTH; ASYMMETRIC HYDROAMINATION; AMIDATE COMPLEXES; LANTHANIDE AMIDES; TERMINAL ALKYNES; MILD AMIDATION; H BONDS; STRUCTURAL-CHARACTERIZATION; MECHANISTIC CONSIDERATIONS;
D O I：
10.6023/cjoc201504024
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
The recent progress on the C-N bond formation reaction catalyzed by organo-rare-earth metal amides includes hydroamination/cyclization, guanidination of carbodiimines and amines, amidation of aldehydes and amines, amidination of amines and nitriles. The mechanisms of these transformations are also described.
引用
收藏
页码：1598 / 1614
页数：17
相关论文
共 131 条
  • [91] Transition metal complexes of guanidinate dianions:: Reactions between guanidines and M(NMe2)5 (M = Ta, Nb)
    Tin, MKT
    Yap, GPA
    Richeson, DS
    [J]. INORGANIC CHEMISTRY, 1998, 37 (26) : 6728 - 6730
  • [92] Rare-Earth Metal Alkyl, Amido, and Cyclopentadienyl Complexes Supported by Imidazolin-2-iminato Ligands: Synthesis, Structural Characterization, and Catalytic Application
    Trambitas, Alexandra G.
    Panda, Tarun K.
    Jenter, Jelena
    Roesky, Peter W.
    Daniliuc, Constantin
    Hrib, Cristian G.
    Jones, Peter G.
    Tamm, Matthias
    [J]. INORGANIC CHEMISTRY, 2010, 49 (05) : 2435 - 2446
  • [93] Bridged bis(amidinate) lanthanide aryloxides: syntheses, structures, and catalytic activity for addition of amines to carbodiimides
    Tu, Jing
    Li, Wenbo
    Xue, Mingqiang
    Zhang, Yong
    Shen, Qi
    [J]. DALTON TRANSACTIONS, 2013, 42 (16) : 5890 - 5901
  • [94] Linked bis(β-diketiminato) yttrium and lanthanum complexes as catalysts in asymmetric hydroamination/cyclization of aminoalkenes (AHA)
    Vitanova, Daniela V.
    Hampel, Frank
    Hultzsch, Kai C.
    [J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2011, 696 (01) : 321 - 330
  • [95] Addition of amines to nitriles catalyzed by ytterbium amides:: An efficient one-step synthesis of monosubstituted N-arylamidines
    Wang, Junfeng
    Xu, Fan
    Cai, Tao
    Shen, Qi
    [J]. ORGANIC LETTERS, 2008, 10 (03) : 445 - 448
  • [96] Anionic Bridged Bis(amidinate) Lithium Lanthanide Complexes: Efficient Bimetallic Catalysts for Mild Amidation of Aldehydes with Amines
    Wang, Junfeng
    Li, Junmei
    Xu, Fan
    Shen, Qi
    [J]. ADVANCED SYNTHESIS & CATALYSIS, 2009, 351 (09) : 1363 - 1370
  • [97] Synthesis of amidolanthanides with new chiral biaryl-based NNO ligands and their use as catalysts for enantioselective hydroamination/cyclization
    Wang, Qiuwen
    Xiang, Li
    Song, Haibin
    Zi, Guofu
    [J]. INORGANIC CHEMISTRY, 2008, 47 (10) : 4319 - 4328
  • [98] Synthesis, structure, and catalytic activity of organolanthanides with chiral biphenyl-based tridentate amidate ligands
    Wang, Qiuwen
    Zhang, Furen
    Song, Haibin
    Zi, Guofu
    [J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2011, 696 (10) : 2186 - 2192
  • [99] Synthesis, structure, and catalytic activity of binuclear lanthanide complexes with chiral NOBIN-based NNO ligands
    Wang, Qiuwen
    Xiang, Li
    Song, Haibin
    Zi, Guofu
    [J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2009, 694 (05) : 691 - 696
  • [100] Rare earth metal bis(silylamide) complexes bearing pyridyl-functionalized indenyl ligand: Synthesis, structure and performance in the living polymerization of L-lactide and rac-lactide
    Wang, Yibin
    Lei, Yinlin
    Chi, Shuhui
    Luo, Yunjie
    [J]. DALTON TRANSACTIONS, 2013, 42 (05) : 1862 - 1871
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