C-N Bond Formation Reaction Catalyzed by Organo-Rare-Earth Metal Amides

被引：12
作者：
Xiao, Yang [1 ]
Wang, Qianyu [1 ]
Zhao, Bei [1 ]
Yao, Yingming [1 ]
机构：
[1] Soochow Univ, Coll Chem Chem Engn & Mat Sci, Key Lab Organ Synth Jiangsu Prov, Suzhou 215123, Peoples R China
来源：
CHINESE JOURNAL OF ORGANIC CHEMISTRY | 2015年 / 35卷 / 08期
基金：
中国国家自然科学基金;
关键词：
rare-earth metal; amides; hydroamination; guanidination; amidation; amidination; INDENYL LIGAND SYNTHESIS; ALKALINE-EARTH; ASYMMETRIC HYDROAMINATION; AMIDATE COMPLEXES; LANTHANIDE AMIDES; TERMINAL ALKYNES; MILD AMIDATION; H BONDS; STRUCTURAL-CHARACTERIZATION; MECHANISTIC CONSIDERATIONS;
D O I：
10.6023/cjoc201504024
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
The recent progress on the C-N bond formation reaction catalyzed by organo-rare-earth metal amides includes hydroamination/cyclization, guanidination of carbodiimines and amines, amidation of aldehydes and amines, amidination of amines and nitriles. The mechanisms of these transformations are also described.
引用
收藏
页码：1598 / 1614
页数：17
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