A carbon-based photocatalyst efficiently converts CO2 to CH4 and C2H2 under visible light

被引:62
|
作者
Wu, Tongshun [1 ]
Zou, Luyi [2 ]
Han, Dongxue [1 ]
Li, Fenghua [1 ]
Zhang, Qixian [1 ]
Niu, Li [1 ]
机构
[1] Chinese Acad Sci, Changchun Inst Appl Chem, Engn Lab Modern Analyt Tech, State Key Lab Electroanalyt Chem, Changchun 130022, Peoples R China
[2] Jilin Univ, Inst Theoret Chem, State Key Lab Theoret & Computat Chem, Changchun 130023, Peoples R China
关键词
SOLAR FUEL PRODUCTION; BILAYER GRAPHENE; REDUCTION; DIOXIDE; METHANE; WATER; HYDROCARBONS; CHALLENGE; OXIDATION; CHEMICALS;
D O I
10.1039/c3gc42454e
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Novel photocatalysts consisting of porphyrin and graphene have been designed to reduce CO2 to hydrocarbons under visible light. These catalysts can (i) effectively reduce CO2 to hydrocarbons, particularly to C2H2; and (ii) selectively control the transfer of photo-generated electrons from graphene to CO2 rather than to H2O.
引用
收藏
页码:2142 / 2146
页数:5
相关论文
共 50 条
  • [1] CoII Cryptates Convert CO2 into CO and CH4 under Visible Light
    Realista, Sara
    Almeida, Janaina C.
    Milheiro, Sofia A.
    Bandeira, Nuno A. G.
    Alves, Luis G.
    Madeira, Filipe
    Calhorda, Maria Jose
    Martinho, Paulo N.
    CHEMISTRY-A EUROPEAN JOURNAL, 2019, 25 (50) : 11670 - 11679
  • [2] A new metal-organic framework for separation of C2H2/CH4 and CO2/CH4 at room temperature
    Duan, Xing
    Zhou, You
    Lv, Ran
    Yu, Ben
    Chen, Haodong
    Ji, Zhenguo
    Cui, Yuanjing
    Yang, Yu
    Qian, Guodong
    JOURNAL OF SOLID STATE CHEMISTRY, 2018, 260 : 31 - 33
  • [3] A photocatalyst for reducing CO2 to CH4
    Chemical Engineering (United States), 2018, 125 (01):
  • [4] Solvent Regulation in Layered Zn-MOFs for C2H2/CO2 and CO2/CH4 Separation
    Zhao, Xingyao
    Chang, Xiaotong
    Qin, Caixian
    Wang, Xiaokang
    Xu, Mingming
    Fan, Weidong
    Meng, Qingguo
    Sun, Daofeng
    MOLECULES, 2025, 30 (05):
  • [5] Bioorganic activated carbon from cashew nut shells for H2 adsorption and H2/CO2, H2/CH4, CO2/CH4, H2/CO2/CH4 selectivity in industrial applications
    Serafin, Jaroslaw
    Dziejarski, Bartosz
    Fonseca-Bermúdez, Óscar Javier
    Giraldo, Liliana
    Sierra-Ramírez, Rocío
    Bonillo, Marta Gil
    Farid, Ghulam
    Moreno-Piraján, Juan Carlos
    International Journal of Hydrogen Energy, 2024, 86 : 662 - 676
  • [6] One Co-MOF with F Active Sites for Separation of C2H2 from CO2, C2H4, and CH4
    Zhang, Xiao-Yu
    Shi, Wen-Juan
    Wang, Gang-Ding
    Hou, Lei
    Wang, Yao-Yu
    INORGANIC CHEMISTRY, 2023, 62 (40) : 16574 - 16581
  • [7] Measurement and Calculation of CO2 Frost Points in CH4 + CO2/CH4 + CO2 + N2/CH4 + CO2 + C2H6 Mixtures at Low Temperatures
    Xiong, Xiaojun
    Lin, Wensheng
    Jia, Rong
    Song, Yang
    Gu, Anzhong
    JOURNAL OF CHEMICAL AND ENGINEERING DATA, 2015, 60 (11): : 3077 - 3086
  • [8] Efficient Visible Light Photocatalytic CO2 Reforming of CH4
    Han, Bing
    Wei, Wei
    Chang, Liang
    Cheng, Peifu
    Hu, Yun Hang
    ACS CATALYSIS, 2016, 6 (02): : 494 - 497
  • [9] Advanced technology converts CH4 and CO2 into gasoline
    不详
    HYDROCARBON PROCESSING, 2010, 89 (08): : 18 - 18
  • [10] Boosting selective C2H2/CH4, C2H4/CH4 and CO2/CH4 adsorption performance via 1,2,3-triazole functionalized triazine-based porous organic polymers
    Liu, Xionghui
    Du, Jianfeng
    Ye, Yu
    Liu, Yuchuan
    Wang, Shun
    Meng, Xianyu
    Song, Xiaowei
    Liang, Zhiqiang
    Yan, Wenfu
    CHINESE JOURNAL OF CHEMICAL ENGINEERING, 2022, 42 : 64 - 72