Fabrication of β-sic quantum dots by photo-assisted electrochemical corrosion of bulk powders

被引:9
作者
Mwania, Munuve [1 ]
Janaky, Csaba [1 ,2 ]
Rajeshwar, Krishnan [1 ]
Kroll, Peter [1 ]
机构
[1] Univ Texas Arlington, Dept Chem & Biochem, Arlington, TX 76019 USA
[2] Univ Szeged, Dept Phys Chem & Mat Sci, H-6720 Szeged, Hungary
基金
美国国家科学基金会;
关键词
Photoelectrochemical corrosion; Luminescence; Semiconductor; Quantum-dot; NANOPARTICLES;
D O I
10.1016/j.elecom.2013.09.020
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
Silicon carbide (SiC) quantum dots (QDs) are eminent candidates for various applications ranging from bioimaging and energy conversion, to optics. In this communication we describe a new top-down method for producing SiC QDs (<10 nm) from bulk powder (>50nm) and slurry. Photo-assisted electrochemical etching is employed to obtain the quantum-sized clusters. We show that the process (hence, the amount of QDs synthesized as well as their size) can be controlled via regulating time as confirmed by both high-resolution transmission electron microscopy and photoluminescence data. The presented method may serve as a new avenue to prepare size-controlled nanoparticles of different semiconductors. (C) 2013 Elsevier B.V. All rights reserved.
引用
收藏
页码:1 / 4
页数:4
相关论文
共 19 条
[1]   Preparation of small silicon carbide quantum dots by wet chemical etching [J].
Beke, David ;
Szekrenyes, Zsolt ;
Balogh, Istvan ;
Czigany, Zsolt ;
Kamaras, Katalin ;
Gali, Adam .
JOURNAL OF MATERIALS RESEARCH, 2013, 28 (01) :44-49
[2]   Characterization of luminescent silicon carbide nanocrystals prepared by reactive bonding and subsequent wet chemical etching [J].
Beke, David ;
Szekrenyes, Zsolt ;
Balogh, Istvan ;
Veres, Miklos ;
Fazakas, Eva ;
Varga, Lajos K. ;
Kamaras, Katalin ;
Czigany, Zsolt ;
Gali, Adam .
APPLIED PHYSICS LETTERS, 2011, 99 (21)
[3]   Photoluminescence of 6H-SiC nanostructures fabricated by electrochemical etching [J].
Botsoa, J. ;
Bluet, J. M. ;
Lysenko, V. ;
Marty, O. ;
Barbier, D. ;
Guillot, G. .
JOURNAL OF APPLIED PHYSICS, 2007, 102 (08)
[4]   Low-dimensional SiC nanostructures: Fabrication, luminescence, and electrical properties [J].
Fan, J. Y. ;
Wu, X. L. ;
Chu, Paul K. .
PROGRESS IN MATERIALS SCIENCE, 2006, 51 (08) :983-1031
[5]   Photoinduced Surface Oxidation and Its Effect on the Exciton Dynamics of CdSe Quantum Dots [J].
Hines, Douglas A. ;
Becker, Matthew A. ;
Kamat, Prashant V. .
JOURNAL OF PHYSICAL CHEMISTRY C, 2012, 116 (24) :13452-13457
[6]   Electrochemical properties of silicon carbide [J].
Lauermann, I ;
Memming, R ;
Meissner, D .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1997, 144 (01) :73-80
[7]   Surface-Dependent, Ligand-Mediated Photochemical Etching of CdSe Nanoplatelets [J].
Lim, Sung Jun ;
Kim, Wonjung ;
Shin, Seung Koo .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2012, 134 (18) :7576-7579
[8]  
Nychyporuk T., 2005, SILICON CARBIDE RE 2, P763
[9]   Ultraviolet photoluminescence from 6H silicon carbide nanoparticles [J].
Rossi, Andrea M. ;
Murphy, Thomas E. ;
Reipa, Vytas .
APPLIED PHYSICS LETTERS, 2008, 92 (25)
[10]   TiO2 Nanotubes: Synthesis and Applications [J].
Roy, Poulomi ;
Berger, Steffen ;
Schmuki, Patrik .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2011, 50 (13) :2904-2939