An unprecedented example of a cis-phosphonodithioato nickel(II) complex built by an extensive hydrogen bonding supramolecular network

被引：32

作者：

Albano, VG

Aragoni, MC

Arca, M

Castellari, C

Demartin, F

Devillanova, FA

Isaia, F

Lippolis, V

Loddo, L

Verani, G

机构：

[1] Cittadella Univ, Dipartimento Chim Inorgan & Analit, I-09042 Monserrato, CA, Italy

[2] Dipartimento Chim G Ciamician, I-40126 Bologna, Italy

[3] Dipartimento Chim Strutturale & Stereochim Inorga, I-20133 Milan, Italy

来源：

CHEMICAL COMMUNICATIONS | 2002年 / 11期

关键词：

D O I：

10.1039/b200414c

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The P-N bond hydrolysis of the 4-methoxyphenyl-ammonium ethylamido-phosphonodithioato ligand during its complexation to Ni-II leads to the first example of phosphonodithioato nickel(II) complex having a cis configuration; this complex is stabilised in the solid state by an extensive and intricate network of hydrogen bondings involving the released ethylenediamine and a water molecule.

引用

页码：1170 / 1171

页数：2