Visible Light Photocatalysis. A Green Choice?

被引:0
作者
Ravelli, Davide [1 ]
Protti, Stefano [1 ]
Fagnoni, Maurizio [1 ]
Albini, Angelo [1 ]
机构
[1] Univ Pavia, Dept Chem, PhotoGreen Lab, I-27100 Pavia, Italy
关键词
Atom Economy; EATOS; Electron Transfer; Green Metrics; Photocatalysis; Process Mass Intensity; Ruthenium complexes; Visible Light; DEHYDROGENATIVE COUPLING REACTIONS; ENANTIOSELECTIVE ALPHA-TRIFLUOROMETHYLATION; CATALYZED OXIDATIVE CYANATION; PHOTOREDOX CATALYSIS; TERTIARY-AMINES; METAL-FREE; EFFICIENT; ARYLATION; ORGANOCATALYSIS; GENERATION;
D O I
10.2174/13852728113179990051
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
The "green" character of a series of reactions carried out under visible light photocatalysis has been evaluated by calculating the Process Mass Intensity (PMI) and by means of the EATOS software. The indexes obtained were likewise calculated for the thermal version of the same reactions for the sake of comparison. The role of solvents, of the photocatalyst used and of the irradiation apparatus are discussed.
引用
收藏
页码:2366 / 2373
页数:8
相关论文
共 50 条
  • [21] Trifluoroethylation of Alkynes: Synthesis of Allylic-CF3 Compounds by Visible-Light Photocatalysis
    Roh, Geum-bee
    Iqbal, Naeem
    Cho, Eun Jin
    CHINESE JOURNAL OF CHEMISTRY, 2016, 34 (05) : 459 - 464
  • [22] Green Light Triggered Radical Annulation for the Synthesis of Indenone by Metal-Free Photocatalysis
    He, Xing
    Ji, Jia-Qi
    Zhao, Meng-Yan
    Ma, Chun-Hua
    Zhang, Dan-Dan
    Xu, Gui-Qing
    Ding, Qing-Jie
    Cui, Zhen-Wei
    Jiang, Yu-Qin
    EUROPEAN JOURNAL OF ORGANIC CHEMISTRY, 2024, 27 (37)
  • [23] Visible light photocatalysis with benzophenone for radical thiol-ene reactions
    Singh, Manjula
    Yadav, Arvind K.
    Yadav, Lal Dhar S.
    Singh, R. K. P.
    TETRAHEDRON LETTERS, 2017, 58 (23) : 2206 - 2208
  • [24] Atom-Transfer Radical Addition to Unactivated Alkenes by using Heterogeneous Visible-Light Photocatalysis
    Mao, Liang-Liang
    Cong, Huan
    CHEMSUSCHEM, 2017, 10 (22) : 4461 - 4464
  • [25] Synthesis of Substituted Oxazoles by Visible-Light Photocatalysis
    Chatterjee, Tanmay
    Cho, Ji Young
    Cho, Eun Jin
    JOURNAL OF ORGANIC CHEMISTRY, 2016, 81 (16) : 6995 - 7000
  • [26] [3+2] Photooxygenation of aryl cyclopropanes via visible light photocatalysis
    Lu, Zhan
    Parrish, Jonathan D.
    Yoon, Tehshik P.
    TETRAHEDRON, 2014, 70 (27-28) : 4270 - 4278
  • [27] VISIBLE LIGHT PHOTOCATALYSIS BY METAL HALIDE COMPLEXES CONTAINING TITANIA AS A SEMICONDUCTOR LIGAND
    Kisch, Horst
    ADVANCES IN INORGANIC CHEMISTRY, VOL 63: INORGANIC PHOTOCHEMISTRY, 2011, 63 : 371 - 393
  • [28] Au clusters-based visible light photocatalysis
    Tan, Chang-Long
    Zhang, Fan
    Li, Yue-Hua
    Tang, Zi-Rong
    Xu, Yi-Jun
    RESEARCH ON CHEMICAL INTERMEDIATES, 2021, 47 (01) : 29 - 50
  • [29] Visible light photocatalysis in chemoselective functionalization of C(sp3)-H bonds enabled by organic dyes
    Wei, Guo
    Basheer, Chanbasha
    Tan, Choon-Hong
    Jiang, Zhiyong
    TETRAHEDRON LETTERS, 2016, 57 (34) : 3801 - 3809
  • [30] Beginning of Visible Light-photocatalysis
    Akita, Munetaka
    JOURNAL OF SYNTHETIC ORGANIC CHEMISTRY JAPAN, 2022, 80 (08) : 782 - 785