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Visible Light Photocatalysis. A Green Choice?
被引:0
作者:
Ravelli, Davide
[1
]
Protti, Stefano
[1
]
Fagnoni, Maurizio
[1
]
Albini, Angelo
[1
]
机构:
[1] Univ Pavia, Dept Chem, PhotoGreen Lab, I-27100 Pavia, Italy
关键词:
Atom Economy;
EATOS;
Electron Transfer;
Green Metrics;
Photocatalysis;
Process Mass Intensity;
Ruthenium complexes;
Visible Light;
DEHYDROGENATIVE COUPLING REACTIONS;
ENANTIOSELECTIVE ALPHA-TRIFLUOROMETHYLATION;
CATALYZED OXIDATIVE CYANATION;
PHOTOREDOX CATALYSIS;
TERTIARY-AMINES;
METAL-FREE;
EFFICIENT;
ARYLATION;
ORGANOCATALYSIS;
GENERATION;
D O I:
10.2174/13852728113179990051
中图分类号:
O62 [有机化学];
学科分类号:
070303 ;
081704 ;
摘要:
The "green" character of a series of reactions carried out under visible light photocatalysis has been evaluated by calculating the Process Mass Intensity (PMI) and by means of the EATOS software. The indexes obtained were likewise calculated for the thermal version of the same reactions for the sake of comparison. The role of solvents, of the photocatalyst used and of the irradiation apparatus are discussed.
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页码:2366 / 2373
页数:8
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