Modelling electric field control of the spin state in the mixed-valence polyoxometalate [GeV14O40]8-

被引：25

作者：

Cardona-Serra, Salvador ^{[1
]}

Clemente-Juan, Juan M. ^{[1
]}

Gaita-Arino, Alejandro ^{[1
]}

Suaud, Nicolas ^{[2
,3
]}

Svoboda, Ondrej ^{[2
,3
]}

Coronado, Eugenio ^{[1
]}

机构：

[1] Univ Valencia, Inst Ciencia Mol ICMol, Paterna 46980, Spain

[2] Univ Toulouse, UPS, Lab Chim & Phys Quant, IRSAMC, F-31062 Toulouse, France

[3] CNRS, UMR 5626, F-31062 Toulouse, France

来源：

CHEMICAL COMMUNICATIONS | 2013年 / 49卷 / 83期

关键词：

HETEROPOLY BLUES; MOLECULAR SPINTRONICS; MAGNETIC MOLECULES; DELOCALIZATION; COMPLEXES; CLUSTERS; PAIRS; NMR;

D O I：

10.1039/c3cc44859b

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The two-electron reduced mixed-valence polyoxometalate [GeV14O40](8-) presents an unusual paramagnetic behaviour as a consequence of the partial trapping of these electrons. The effect of applying an electric field is that of inducing antiferromagnetic coupling between the two delocalized electronic spins.

引用

页码：9621 / 9623

页数：3

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