Oxidative Catalytic Coupling Reactions: Selective Formation of C-C and C-X Bonds Using Radical Processes

被引:91
作者
Liu, Qiang [1 ]
Jackstell, Ralf [1 ]
Beller, Matthias [1 ]
机构
[1] Univ Rostock, Leibniz Inst Katalyse, D-18059 Rostock, Germany
关键词
CC bonds; CX bonds; oxidative coupling; radical reactions; sustainable chemistry; FUNCTIONALIZATION; COPPER; TETRAHYDROFURAN; PALLADIUM; ALKENES; PD;
D O I
10.1002/anie.201307865
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Radicals can do it! Oxidative coupling processes that proceed by a single-electron-transfer mechanism have been established. Recently developed methods demonstrate the ability of non-precious-metal catalysts to act as efficient catalysts for such transformations. This concept provides a sustainable approach for the construction of C-C and C-X bonds. Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
引用
收藏
页码:13871 / 13873
页数:3
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