Microwave assisted synthesis in coordination chemistry

被引:16
作者
Pons-Balague, Alba [1 ]
Heras Ojea, Maria Jose [1 ]
Ledezma-Gairaud, Marisol [2 ,3 ]
Reta Maneru, Daniel [1 ]
Teat, Simon J. [4 ]
Sanchez Costa, Jose [1 ]
Aromi, Guillem [1 ]
Carolina Sanudo, E. [1 ]
机构
[1] Univ Barcelona, Dept Quim Inorgan, Barcelona 08028, Spain
[2] Univ Costa Rica, Escuela Quim, San Jose, Costa Rica
[3] Univ Costa Rica, CELEQ, Ctr Electroquim & Energia Quim, San Jose, Costa Rica
[4] Univ Calif Berkeley, Lawrence Berkeley Natl Lab, Adv Light Source, Berkeley, CA 94720 USA
关键词
Microwave assisted synthesis; Coordination chemistry; Magnetism; MAGNETIC-PROPERTIES; COMPLEXES; CLUSTER; OCTANUCLEAR; TRIANGLES; MANGANESE; LIGAND; METAL; STATE; CAGE;
D O I
10.1016/j.poly.2012.07.051
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Microwave assisted synthesis is presented as a very useful tool in coordination chemistry. The synthesis assisted by microwave radiation has proven to be an excellent tool for the achievement of new structural types of polynuclear transition metal complexes. Several reaction conditions are studied and the results reported here. New examples of complexes of Mn, Co and Ni are reported along with their characterization. (C) 2012 Elsevier Ltd. All rights reserved.
引用
收藏
页码:781 / 787
页数:7
相关论文
共 34 条
  • [11] HIGH-SPIN MOLECULES - UNUSUAL MAGNETIC-SUSCEPTIBILITY RELAXATION EFFECTS IN [MN12O12(O(2)CET)(16)(H2O)(3)] (S=9) AND THE ONE-ELECTRON REDUCTION PRODUCT (PPH4)[MN12O12(O(2)CET)(16)(H2O)(4)] (S=19/2)
    EPPLEY, HJ
    TSAI, HL
    DEVRIES, N
    FOLTING, K
    CHRISTOU, G
    HENDRICKSON, DN
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1995, 117 (01) : 301 - 317
  • [12] A cube in a tetrahedron:: Microwave-assisted synthesis of an octametallic FeIII cluster
    Gass, Ian A.
    Milios, Constantinos J.
    Whittaker, A. Gavin
    Fabbiani, Francesca P. A.
    Parsons, Simon
    Murrie, Mark
    Perlepes, Spyros P.
    Brechin, Euan K.
    [J]. INORGANIC CHEMISTRY, 2006, 45 (14) : 5281 - 5283
  • [13] Microwave-enhanced reaction rates for nanoparticle synthesis
    Gerbec, JA
    Magana, D
    Washington, A
    Strouse, GF
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2005, 127 (45) : 15791 - 15800
  • [14] Microwave-Assisted Synthesis of Metal-Organic Frameworks
    Klinowski, Jacek
    Almeida Paz, Filipe A.
    Silva, Patricia
    Rocha, Joao
    [J]. DALTON TRANSACTIONS, 2011, 40 (02) : 321 - 330
  • [15] Solvothermal synthesis of paramagnetic molecular clusters
    Laye, RH
    McInnes, EJL
    [J]. EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2004, (14) : 2811 - 2818
  • [16] Kondo resonance in a single-molecule transistor
    Liang, WJ
    Shores, MP
    Bockrath, M
    Long, JR
    Park, H
    [J]. NATURE, 2002, 417 (6890) : 725 - 729
  • [17] Loupy A., 2002, MICROWAVES ORGANIC S
  • [18] Mabbs FE, 1999, CHEM COMMUN, P643
  • [19] High-spin M2+ carboxylate triangles from the microwave
    Milios, Constantinos J.
    Prescimone, Alessandro
    Sanchez-Benitez, J.
    Parsons, Simon
    Murrie, Mark
    Brechin, Euan K.
    [J]. INORGANIC CHEMISTRY, 2006, 45 (18) : 7053 - 7055
  • [20] Polynuclear nickel(II) complexes:: Preparation and magnetic properties of NiII4, NiII5, and NiII6 species with ligands containing O∧X∧O (X = S, Se or N) donor atoms
    Paine, TK
    Rentschler, E
    Weyhermüller, T
    Chaudhuri, P
    [J]. EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2003, (17) : 3167 - 3178