Microwave assisted synthesis in coordination chemistry

被引:16
作者
Pons-Balague, Alba [1 ]
Heras Ojea, Maria Jose [1 ]
Ledezma-Gairaud, Marisol [2 ,3 ]
Reta Maneru, Daniel [1 ]
Teat, Simon J. [4 ]
Sanchez Costa, Jose [1 ]
Aromi, Guillem [1 ]
Carolina Sanudo, E. [1 ]
机构
[1] Univ Barcelona, Dept Quim Inorgan, Barcelona 08028, Spain
[2] Univ Costa Rica, Escuela Quim, San Jose, Costa Rica
[3] Univ Costa Rica, CELEQ, Ctr Electroquim & Energia Quim, San Jose, Costa Rica
[4] Univ Calif Berkeley, Lawrence Berkeley Natl Lab, Adv Light Source, Berkeley, CA 94720 USA
关键词
Microwave assisted synthesis; Coordination chemistry; Magnetism; MAGNETIC-PROPERTIES; COMPLEXES; CLUSTER; OCTANUCLEAR; TRIANGLES; MANGANESE; LIGAND; METAL; STATE; CAGE;
D O I
10.1016/j.poly.2012.07.051
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Microwave assisted synthesis is presented as a very useful tool in coordination chemistry. The synthesis assisted by microwave radiation has proven to be an excellent tool for the achievement of new structural types of polynuclear transition metal complexes. Several reaction conditions are studied and the results reported here. New examples of complexes of Mn, Co and Ni are reported along with their characterization. (C) 2012 Elsevier Ltd. All rights reserved.
引用
收藏
页码:781 / 787
页数:7
相关论文
共 34 条
  • [1] Synthesis of 3d metallic single-molecule magnets
    Aromi, Guillem
    Brechin, Euan K.
    [J]. SINGLE-MOLECULE MAGNETS AND RELATED PHENOMENA, 2006, 122 : 1 - 67
  • [2] Atkinson IM, 1999, CHEM COMMUN, P285
  • [3] Molecular spintronics using single-molecule magnets
    Bogani, Lapo
    Wernsdorfer, Wolfgang
    [J]. NATURE MATERIALS, 2008, 7 (03) : 179 - 186
  • [4] Nanoscale cages of manganese and nickel with "rock salt" cores
    Brechin, EK
    Clegg, W
    Murrie, M
    Parsons, S
    Teat, SJ
    Winpenny, REP
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1998, 120 (29) : 7365 - 7366
  • [5] Carlin R.L., 1986, MAGNETOCHEMISTRY, P67
  • [6] Synthesis and structure of linear hexanuclear manganese (II) benzoate cluster
    Chen, CN
    Chen, JT
    Zhu, HP
    Huang, ZX
    Liu, QT
    [J]. SCIENCE IN CHINA SERIES B-CHEMISTRY, 2001, 44 (03): : 320 - 327
  • [7] Synthesis and studies of a trinuclear Mn(II) carboxylate complex
    Christian, P
    Rajaraman, G
    Harrison, A
    Helliwell, M
    McDouall, JJW
    Raftery, J
    Winpenny, REP
    [J]. DALTON TRANSACTIONS, 2004, (16) : 2550 - 2555
  • [8] Constantinos J. M., 2006, INORG CHEM, V45, P5272
  • [9] High-temperature reactions of metal triangles: The influence of counterion, ligand, and metal on the structure observed
    Coxall, RA
    Parkin, A
    Parsons, S
    Smith, AA
    Timco, GA
    Winpenny, REP
    [J]. JOURNAL OF SOLID STATE CHEMISTRY, 2001, 159 (02) : 321 - 327
  • [10] THE [CO4O4](4+) CUBANE AS A QUADRUPLY-BRIDGING UNIT - THE MIXED-VALENCE CLUSTER [CO8O4(O(2)CPH)(12)(SOLV)(4)] (SOLV=DMF, MECN, H2O)
    DIMITROU, K
    SUN, JS
    FOLTING, K
    CHRISTOU, G
    [J]. INORGANIC CHEMISTRY, 1995, 34 (16) : 4160 - 4166