Facile and rapid synthesis of RGO-In2S3 composites with enhanced cyclability and high capacity for lithium storage

被引:55
作者
Ye, Fangmin [1 ,2 ]
Du, Gaohui [3 ]
Jiang, Zhoufeng [1 ,2 ]
Zhong, Yijun [3 ]
Wang, Xiaodong [1 ,2 ]
Cao, Qingping [1 ,2 ]
Jiang, J. Z. [1 ,2 ]
机构
[1] Zhejiang Univ, ICNSM, Hangzhou 310027, Peoples R China
[2] Zhejiang Univ, Lab New Struct Mat, Dept Mat Sci & Engn, Hangzhou 310027, Peoples R China
[3] Zhejiang Normal Univ, Inst Phys Chem, Jinhua 321004, Peoples R China
基金
中国国家自然科学基金;
关键词
ION BATTERIES; ANODE MATERIALS; ELECTROCHEMICAL PROPERTIES; OXIDE NANOPARTICLES; MORPHOLOGY CONTROL; CARBON NANOTUBES; SOLAR-CELLS; GRAPHENE; SNO2; IN2S3;
D O I
10.1039/c2nr32174b
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A sheet-on-sheet reduced graphene oxide-beta-In2S3 (RGO-In2S3) composite, was successfully synthesized via a one-stepmild method. This fresh composite used as an anode material exhibits enhanced cyclability and specific capacity for lithium storage. These results are linked with the intrinsic layered structure of beta-In2S3 sheets and the effective combination of beta-In2S3 and RGO sheets. This results in a high specific surface area and good conductivity of RGO-In2S3 composites, with higher transport rates of electrolyte ions and electrons, and a more effective electrochemical reaction of the active material. This facile and rapid synthesis method is a promising route for a large-scale production of graphene-based metal sulfides, which could be used as electrode materials for Li-ion batteries.
引用
收藏
页码:7354 / 7357
页数:4
相关论文
共 38 条
[11]   Hollow Iron Oxide Nanoparticles for Application in Lithium Ion Batteries [J].
Koo, Bonil ;
Xiong, Hui ;
Slater, Michael D. ;
Prakapenka, Vitali B. ;
Baasubramanian, Mahalingam ;
Podsiadlo, Paul ;
Johnson, Christopher S. ;
Rajh, Tijana ;
Shevchenko, Elena V. .
NANO LETTERS, 2012, 12 (05) :2429-2435
[12]   Improved electrode performance of mesoporous β-In2S3 microspheres for lithium ion batteries using carbon coated microspheres [J].
Li, Guang ;
Liu, Huajie .
JOURNAL OF MATERIALS CHEMISTRY, 2011, 21 (45) :18398-18402
[13]   Solvothermal preparation and visible photocatalytic activity of polycrystalline β-In2S3 nanotubes [J].
Liu, Guodong ;
Jiao, Xiuling ;
Qin, Zhenhua ;
Chen, Dairong .
CRYSTENGCOMM, 2011, 13 (01) :182-187
[14]   Morphology Control of β-In2S3 from Chrysanthemum-Like Microspheres to Hollow Microspheres: Synthesis and Electrochemical Properties [J].
Liu, Lu ;
Liu, Huajie ;
Kou, Hui-Zhong ;
Wang, Yuqiu ;
Zhou, Zhen ;
Ren, Manman ;
Ge, Ming ;
He, Xiwen .
CRYSTAL GROWTH & DESIGN, 2009, 9 (01) :113-117
[15]   Template-free synthesis of SnO2 hollow nanostructures with high lithium storage capacity [J].
Lou, Xiong Wen ;
Wang, Yong ;
Yuan, Chongli ;
Lee, Jim Yang ;
Archer, Lynden A. .
ADVANCED MATERIALS, 2006, 18 (17) :2325-+
[16]   Designed Synthesis of Coaxial SnO2@carbon Hollow Nanospheres for Highly Reversible Lithium Storage [J].
Lou, Xiong Wen ;
Li, Chang Ming ;
Archer, Lynden A. .
ADVANCED MATERIALS, 2009, 21 (24) :2536-+
[17]   Two dimensional graphene-SnS2 hybrids with superior rate capability for lithium ion storage [J].
Luo, Bin ;
Fang, Yan ;
Wang, Bin ;
Zhou, Jisheng ;
Song, Huaihe ;
Zhi, Linjie .
ENERGY & ENVIRONMENTAL SCIENCE, 2012, 5 (01) :5226-5230
[18]   Hybrid Tin Oxide Nanowires as Stable and High Capacity Anodes for Li-Ion Batteries [J].
Meduri, Praveen ;
Pendyala, Chandrashekhar ;
Kumar, Vivekanand ;
Sumanasekera, Gamin U. ;
Sunkara, Mahendra K. .
NANO LETTERS, 2009, 9 (02) :612-616
[19]   High-efficiency copper indium gallium diselenide (CIGS) solar cells with indium sulfide buffer layers deposited by atomic layer chemical vapor deposition (ALCVD) [J].
Naghavi, N ;
Spiering, S ;
Powalla, M ;
Cavana, B ;
Lincot, D .
PROGRESS IN PHOTOVOLTAICS, 2003, 11 (07) :437-443
[20]   Electric field effect in atomically thin carbon films [J].
Novoselov, KS ;
Geim, AK ;
Morozov, SV ;
Jiang, D ;
Zhang, Y ;
Dubonos, SV ;
Grigorieva, IV ;
Firsov, AA .
SCIENCE, 2004, 306 (5696) :666-669