A 3D-diamond-like tetrazole-based Zn(II) coordination polymer: Crystal structure, nonlinear optical effect and luminescent property

被引：57
作者：
Chen, Qi-Yong [1 ,2 ]
Li, Yan [1 ,2 ]
Zheng, Fa-Kun [1 ]
Zou, Wen-Qiang [1 ]
Wu, Mei-Feng [1 ,2 ]
Guo, Guo-Cong [1 ]
Wu, A-Qing [1 ]
Huang, Jin-Shun [1 ]
机构：
[1] Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Fujian, Peoples R China
[2] Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China
来源：
INORGANIC CHEMISTRY COMMUNICATIONS | 2008年 / 11卷 / 09期
基金：
中国国家自然科学基金;
关键词：
coordination polymer; 1H-tetrazole-5-formic acid; crystal structure; diamond-like network;
D O I：
10.1016/j.inoche.2008.05.009
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A tetrazole-based Zn(II) coordination polymer, [Zn(tzf)(2)](n) 1(Htzf= 1H-tetrazole-5-formic acid), was synthesized by reaction of ZnCl2 and Htzf, and structurally characterized by single-crystal X-ray diffraction. Polymer 1 features a 3D-diamond-like net formed by the linkage of Zn(II) atoms and tetrazole groups. The carboxylate O atoms in tzf ligand remain uncoordinated. Polymer 1 displays a second harmonic generation response, which is ca. 1.1 times that of KDP (KH2PO4). The photoluminescent analysis reveals that 1 exhibits strong blue emission resulting from intraligand charge transition. (C) 2008 Elsevier B.V. All rights reserved.
引用
收藏
页码：969 / 971
页数：3
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