The synthesis, structure and properties of a new compound with 1D linear chain arsenomolybdate anion building block

被引：12
|
作者：
Zhao, Wenqi [1 ,2 ]
Su, Zhanhua [1 ,2 ]
Zhao, Zhifeng [3 ]
Cong, Bowen [1 ,2 ]
Xia, Lin [1 ,2 ]
Zhou, Baibin [1 ,2 ]
机构：
[1] Harbin Normal Univ, Sch Chem & Chem Engn, Key Lab Photon & Elect Bandgap Mat, Minist Educ, Harbin 150025, Heilongjiang Pr, Peoples R China
[2] Harbin Normal Univ, Coll Heilongjiang Prov, Key Lab Synth Funct Mat & Green Catalysis, Harbin 150025, Peoples R China
[3] Univ Sci & Technol Heilongjiang, Coll Mat Sci & Engn, Harbin 150022, Peoples R China
来源：
INORGANIC CHEMISTRY COMMUNICATIONS | 2015年 / 61卷
基金：
中国国家自然科学基金;
关键词：
Arsenomolybdate; Electrocatalytic; Photocatalytic; CRYSTAL-STRUCTURE; LIGAND; COMPLEXES; CATALYST; CLUSTER; SERIES; POM;
D O I：
10.1016/j.inoche.2015.09.008
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The new inorganic-organic hybrid arsenomolybdate {Cu(2,2'-bPY)}(2){H2As2MO2O14} (2,2'-bPy = 2,2'-bipyridine) (1) has been hydrothermally synthesized and characterized by single-crystal X-ray diffraction analysis, elemental analyses, X-ray powder diffraction (XRPD), IR spectroscopy, UV spectroscopy, XPS spectroscopy and thermogravimetric analysis (TG). Compound 1 presents an infinite 1D chain structure based on the unprecedented H2As2MO2O14}(4-) fragment and transition-metal complex {Cu(2,2'-bpy)}(2+). Compound 1 displays obvious electrocatalytic activities toward the reduction of nitrite and better photocatalytic activities for the degradation of methylene blue. (C) 2015 Elsevier B.V. All rights reserved.
引用
收藏
页码：118 / 122
页数：5
相关论文
共 50 条
  • [31] Synthesis, crystal structure and magnetic properties of 1D chain Cu(II) complex with the single-μ-chloro bridging
    Li, Xi-Li
    Liu, Bao-Lin
    Song, You
    INORGANIC CHEMISTRY COMMUNICATIONS, 2008, 11 (09) : 1100 - 1102
  • [32] 1D nickel(II) coordination polymer with pyrimidine and pivalate bridges: Synthesis, structure and magnetic properties
    Evstifeev, Igor S.
    Kiskin, Mikhail A.
    Mironov, Vladimir S.
    Bogomyakov, Artem S.
    Sidorov, Aleksei A.
    Novotortsev, Vladimir M.
    Eremenko, Igor L.
    INORGANIC CHEMISTRY COMMUNICATIONS, 2010, 13 (04) : 498 - 501
  • [33] Synthesis, Crystal Structure and Properties of 1D Manganese(II) Coordination Polymer
    Fang Xiang-Qian
    Chen Peng-Gang
    Zhu Zhi-Biao
    Deng Zhao-Peng
    Gao Shan
    CHINESE JOURNAL OF INORGANIC CHEMISTRY, 2011, 27 (09) : 1733 - 1737
  • [34] Synthesis, crystal structure and magnetic properties of a cyanide-bridged FeIII-MnIII bimetallic chain based on [Fe(bipy)(CN)4]- building block
    Xu, Yan
    Shen, Xiao-Ping
    Zhou, Hu
    Shu, He-Qing
    Li, Wenxian
    Yuan, Ai-Hua
    JOURNAL OF MOLECULAR STRUCTURE, 2009, 921 (1-3) : 341 - 345
  • [35] A new Cu/Zn carboxylato-bridged 1D polymer: Direct synthesis, X-ray structure and magnetic properties
    Buvaylo, Elena A.
    Kokozay, Volodymyr N.
    Vassilyeva, Olga Yu
    Skelton, Brian W.
    Jezierska, Julia
    Ozarowski, Andrew
    INORGANICA CHIMICA ACTA, 2011, 373 (01) : 27 - 31
  • [36] Solvothermal synthesis, structure and characterization of 1D chain and 2D layered rare earth sulfates in the presence of cyclic diamines
    Ge, Gen-Wu
    Qi, Zhi-Yuan
    Ni, Zhi-Gang
    Li, Yi-Zhi
    Du, Hong-Bin
    You, Xiao-Zeng
    INORGANIC CHEMISTRY COMMUNICATIONS, 2012, 20 : 228 - 233
  • [37] Synthesis, Structure and Photoluminescence of [Cu(acac)(dppe)]n with Novel 1D Zigzag Chain-Like Motif
    Xie, Y. -M.
    Wu, J. -H.
    JOURNAL OF THE IRANIAN CHEMICAL SOCIETY, 2009, 6 (01) : 82 - 87
  • [38] A New 1D Chained Coordination Polymer: Synthesis, Crystal Structure, Antitumor Activity and Luminescent Property
    Tai, Xi-Shi
    You, Hai-Ying
    CRYSTALS, 2015, 5 (04): : 608 - 616
  • [39] Solvothermal synthesis, crystal structure and properties of three new 1D and 3D organically templated lanthanide sulfates
    Fu, Jie
    Zheng, Lei
    Zhang, Zhibin
    Xu, Yan
    INORGANICA CHIMICA ACTA, 2012, 383 : 112 - 117
  • [40] Isolation of a Metastable Intermediate in a Heterometallic CuII-HgII 1D Polymeric Chain: Synthesis, Crystal Structure, and Photophysical Properties
    Mobin, Shaikh M.
    Mishra, Veenu
    Chaudhary, Archana
    INORGANIC CHEMISTRY, 2015, 54 (04) : 1293 - 1299
12345