The synthesis, structure and properties of a new compound with 1D linear chain arsenomolybdate anion building block

被引：12

作者：

Zhao, Wenqi ^{[1
,2
]}

Su, Zhanhua ^{[1
,2
]}

Zhao, Zhifeng ^{[3
]}

Cong, Bowen ^{[1
,2
]}

Xia, Lin ^{[1
,2
]}

Zhou, Baibin ^{[1
,2
]}

机构：

[1] Harbin Normal Univ, Sch Chem & Chem Engn, Key Lab Photon & Elect Bandgap Mat, Minist Educ, Harbin 150025, Heilongjiang Pr, Peoples R China

[2] Harbin Normal Univ, Coll Heilongjiang Prov, Key Lab Synth Funct Mat & Green Catalysis, Harbin 150025, Peoples R China

[3] Univ Sci & Technol Heilongjiang, Coll Mat Sci & Engn, Harbin 150022, Peoples R China

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 2015年 / 61卷

基金：

中国国家自然科学基金;

关键词：

Arsenomolybdate; Electrocatalytic; Photocatalytic; CRYSTAL-STRUCTURE; LIGAND; COMPLEXES; CATALYST; CLUSTER; SERIES; POM;

D O I：

10.1016/j.inoche.2015.09.008

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The new inorganic-organic hybrid arsenomolybdate {Cu(2,2'-bPY)}(2){H2As2MO2O14} (2,2'-bPy = 2,2'-bipyridine) (1) has been hydrothermally synthesized and characterized by single-crystal X-ray diffraction analysis, elemental analyses, X-ray powder diffraction (XRPD), IR spectroscopy, UV spectroscopy, XPS spectroscopy and thermogravimetric analysis (TG). Compound 1 presents an infinite 1D chain structure based on the unprecedented H2As2MO2O14}(4-) fragment and transition-metal complex {Cu(2,2'-bpy)}(2+). Compound 1 displays obvious electrocatalytic activities toward the reduction of nitrite and better photocatalytic activities for the degradation of methylene blue. (C) 2015 Elsevier B.V. All rights reserved.

引用

页码：118 / 122

页数：5