Easy and efficient tuning of the photochromic properties of 1,2-bis[5′-methyl-2′-(2"-pyridyl)thiazolyl]perfluorocyclopentene

被引:4
|
作者
Giraud, Marion [1 ]
Leaustic, Anne [1 ]
Guillot, Regis [1 ]
Yu, Pei [1 ]
Maurel, Francois [2 ]
Nakatani, Keitaro [3 ]
机构
[1] Univ Paris 11, ICMMO, UMR 8182, F-91405 Orsay, France
[2] Univ Paris Diderot, ITODYS, UMR 7086, F-75205 Paris, France
[3] ENS Cachan, UMR 8531, PPSM, F-94235 Cachan, France
关键词
Photochromism; Dithiazolylethene; Pyridine oxide; DFT; NONLINEAR-OPTICAL PROPERTIES; REVERSIBLE PHOTOCYCLIZATION; DITHIENYLETHENE DERIVATIVES; DIARYLETHENE DERIVATIVES; NONDESTRUCTIVE READOUT; MOLECULAR SWITCHES; ELECTRON-TRANSFER; SINGLE-CRYSTALS; LIGANDS; FLUORESCENCE;
D O I
10.1016/j.tetlet.2009.01.078
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Photochromic properties of the tilted compound could be easily tuned by simple oxidation of the peripheral pyridine groups by mCBPA. The mono- and bis-oxidized dithiazolylethenes were found to display both Solution and single crystalline state photochromisms. (C) 2009 Elsevier Ltd. All rights reserved.
引用
收藏
页码:1485 / 1489
页数:5
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