A fluorescein-based probe with high selectivity and sensitivity for sulfite detection in aqueous solution

被引：75

作者：

Ma, Xing ^{[1
,2
]}

Liu, Chunxia ^{[1
]}

Shan, Qiuli ^{[1
]}

Wei, Guohua ^{[1
]}

Wei, Dongbin ^{[1
]}

Du, Yuguo ^{[1
,2
]}

机构：

[1] Chinese Acad Sci, Ecoenvironm Sci Res Ctr, State Key Lab Environm Chem & Ecotoxicol, Beijing 100085, Peoples R China

[2] Univ Chinese Acad Sci, Coll Chem & Chem Engn, Beijing 100049, Peoples R China

来源：

SENSORS AND ACTUATORS B-CHEMICAL | 2013年 / 188卷

基金：

中国国家自然科学基金;

关键词：

Chemodosimeter; Sulfite; Fluorescein; Levulinyl cleavage; FLOW-INJECTION ANALYSIS; ION CHROMATOGRAPHY; MODIFIED ELECTRODE; FAR-RED; WINE; DEPROTECTION; BEVERAGES; OXIDATION; FOOD;

D O I：

10.1016/j.snb.2013.08.007

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

A "turn-on" fluorescein-based probe for sulfite detection has been established employing SO32- promoted levulinyl cleavage and concurrent generation of fluorescein. The synthesized probe exhibits high SO32- selectivity over fourteen other anion ions, and the satisfactory detection limit was 0.80 mg/L in aqueous media containing co-solvent CH3CN (1%, v/v). The probe is successfully applied for the detection of sulfite in white wine. (C) 2013 Published by Elsevier B.V.

引用

页码：1196 / 1200

页数：5

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