A fluorescein-based probe with high selectivity and sensitivity for sulfite detection in aqueous solution

被引：75
|
作者：
Ma, Xing [1 ,2 ]
Liu, Chunxia [1 ]
Shan, Qiuli [1 ]
Wei, Guohua [1 ]
Wei, Dongbin [1 ]
Du, Yuguo [1 ,2 ]
机构：
[1] Chinese Acad Sci, Ecoenvironm Sci Res Ctr, State Key Lab Environm Chem & Ecotoxicol, Beijing 100085, Peoples R China
[2] Univ Chinese Acad Sci, Coll Chem & Chem Engn, Beijing 100049, Peoples R China
来源：
SENSORS AND ACTUATORS B-CHEMICAL | 2013年 / 188卷
基金：
中国国家自然科学基金;
关键词：
Chemodosimeter; Sulfite; Fluorescein; Levulinyl cleavage; FLOW-INJECTION ANALYSIS; ION CHROMATOGRAPHY; MODIFIED ELECTRODE; FAR-RED; WINE; DEPROTECTION; BEVERAGES; OXIDATION; FOOD;
D O I：
10.1016/j.snb.2013.08.007
中图分类号：
O65 [分析化学];
学科分类号：
070302 ; 081704 ;
摘要：
A "turn-on" fluorescein-based probe for sulfite detection has been established employing SO32- promoted levulinyl cleavage and concurrent generation of fluorescein. The synthesized probe exhibits high SO32- selectivity over fourteen other anion ions, and the satisfactory detection limit was 0.80 mg/L in aqueous media containing co-solvent CH3CN (1%, v/v). The probe is successfully applied for the detection of sulfite in white wine. (C) 2013 Published by Elsevier B.V.
引用
收藏
页码：1196 / 1200
页数：5
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