Bipolar membranes: A review on principles, latest developments, and applications

被引：377

作者：

Parnamae, R. ^{[1
]}

Mareev, S. ^{[2
]}

Nikonenko, V ^{[2
]}

Melnikov, S. ^{[2
]}

Sheldeshov, N. ^{[2
]}

Zabolotskii, V ^{[2
]}

Hamelers, H. V. M. ^{[1
]}

Tedesco, M. ^{[1
]}

机构：

[1] Wetsus, European Ctr Excellence Sustainable Water Technol, Oostergoweg 9, NL-8911 MA Leeuwarden, Netherlands

[2] Kuban State Univ, Stavropolskaya St 149, Krasnodar 350040, Russia

来源：

JOURNAL OF MEMBRANE SCIENCE | 2021年 / 617卷

基金：

俄罗斯科学基金会; 欧盟地平线“2020”;

关键词：

Bipolar membrane electrodialysis; Water dissociation; Bipolar junction; Current rectification; pH control; Reverse bias; ION-EXCHANGE MEMBRANES; ELECTROCHEMICAL IMPEDANCE SPECTROSCOPY; CATALYTIC WATER DISSOCIATION; STARBURST DENDRIMER PAMAM; FIXED CHARGE MEMBRANES; CITRIC-ACID PRODUCTION; INTERMEDIATE LAYER; SODIUM-HYDROXIDE; ELECTRIC-FIELD; FUEL-CELL;

D O I：

10.1016/j.memsci.2020.118538

中图分类号：

TQ [化学工业];

学科分类号：

0817 ;

摘要：

Bipolar membranes (BPMs) are a special class of ion-exchange membranes constituted by a cationand an anion exchange layer, allowing the generation of protons and hydroxide ions via a water dissociation mechanism. Such unique feature makes bipolar membranes attractive for a variety of applications in many sectors, such as (bio) chemical industry, food processing, environmental protection, and energy conversion and storage, among others. Research and development on BPMs over the past two decades have created a growing market with commercial BPMs available today from multiple manufacturers. Moreover, BPMs are rapidly gaining attention for their technical, environmental, and economical advancements compared to conventional processes for the production of acid and base, or local pH control. This review article aims to provide an overall understanding of BPM technology by describing the current state of the art on membrane synthesis, properties, theoretical models, and applications, based on the last 70 years of scientific publications and patents in this field. Optimised BPM properties are discussed, together with a summary of the advances in BPM fabrication to attain the targeted optimised characteristics. Furthermore, novel BPM applications are presented, including a list of shortcomings of current membranes that need to be overcome to unlock new promising applications.

引用

页数：25

共 342 条

[91] Self-crosslinking for dimensionally stable and solvent-resistant quaternary phosphonium based hydroxide exchange membranes [J].