A straightforward double coupling of furan moieties onto epoxidized triglycerides: synthesis of monomers based on two renewable resources

被引:26
作者
Gandini, Alessandro [1 ,2 ]
Lacerda, Talita M. [1 ,2 ]
Carvalho, Antonio J. F. [1 ]
机构
[1] Univ Sao Paulo, Escola Engn, BR-13566590 Sao Carlos, SP, Brazil
[2] Univ Sao Paulo, Inst Quim Sao Carlos, BR-13566590 Sao Carlos, SP, Brazil
基金
巴西圣保罗研究基金会;
关键词
BEARING FURAN; OIL; POLYMERS; POLYMERIZATION; POLYURETHANES;
D O I
10.1039/c3gc40358k
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The bulk reaction of 2-furfuryl amine with epoxidized linseed oil took place at both its ester moieties (aminolysis) and oxirane groups (ring opening) producing three fatty acid furan amides incorporating further furan heterocycles along their chains. These reactions were followed spectroscopically and the ensuing monomers used in Diels-Alder reversible polycondensations.
引用
收藏
页码:1514 / 1519
页数:6
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