Polyoxometalate-stabilized, water dispersible Fe2Pt magnetic nanoparticles

被引:19
作者
Seemann, K. M. [1 ,2 ,3 ,4 ]
Bauer, A. [1 ]
Kindervater, J. [1 ]
Meyer, M. [5 ,6 ]
Besson, C. [3 ,4 ,7 ]
Luysberg, M. [8 ]
Durkin, P. [9 ]
Pyckhout-Hintzen, W. [5 ,6 ]
Budisa, N. [9 ]
Georgii, R. [1 ,2 ]
Schneider, C. M. [3 ,4 ]
Koegerler, P. [3 ,4 ,7 ]
机构
[1] Tech Univ Munich, Phys Dept E21, D-85748 Garching, Germany
[2] Tech Univ Munich, Forsch Neutronenquelle Heinz Maier Leibnitz, D-85748 Garching, Germany
[3] Forschungszentrum Julich, Peter Grunberg Inst PGI 6, D-52425 Julich, Germany
[4] Forschungszentrum Julich, JARA FIT, D-52425 Julich, Germany
[5] Forschungszentrum Julich, Julich Ctr Neutron Sci JCNS 1, D-52425 Julich, Germany
[6] Forschungszentrum Julich, Inst Complex Syst ICS 1, D-52425 Julich, Germany
[7] Rhein Westfal TH Aachen, Inst Anorgan Chem, D-52074 Aachen, Germany
[8] Forschungszentrum Julich, Ernst Ruska Ctr Microscopy & Spect Electrons, Peter Grunberg Inst PGI 5, D-52425 Julich, Germany
[9] Tech Univ Berlin, Inst Organ Chem, D-10585 Berlin, Germany
关键词
QUANTUM DOTS; SURFACE; CATALYSIS;
D O I
10.1039/c3nr33374d
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Magnetic Fe2Pt core-shell nanoparticles with 2 nm cores were synthesized with a monolayer coating of silicotungstate Keggin clusters. The core-shell composition is substantiated by structural analysis performed using high-resolution scanning transmission electron microscopy (HR-STEM) and small angle X-ray scattering (SAXS) in a liquid suspension. The molecular metal oxide cluster shell introduces an enhanced dispersibility of the magnetic Fe-Pt core-shell nanoparticles in aqueous media and thereby opens up new routes to nanoparticle bio-functionalization, for example, using pre-functionalized polyoxometalates.
引用
收藏
页码:2511 / 2519
页数:9
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