Amperometric biosensors based on dehydrogenase/NAD and heterocyclic quinones

被引：11

作者：

Geng, L

Boguslavsky, LI

Kovalev, IP

Sahni, SK

Kalash, H

Skotheim, TA

Lee, HS

Laurinavicius, V

机构：

[1] MOLTECH CORP, STONY BROOK, NY 11790 USA

[2] BROOKHAVEN NATL LAB, UPTON, NY 11973 USA

[3] INST BIOCHEM, LT-2021 VILNIUS, LITHUANIA

来源：

BIOSENSORS & BIOELECTRONICS | 1996年 / 11卷 / 12期

关键词：

biosensors; glucose determination; NADH electro-oxidation; glucose dehydrogenase; quinones;

D O I：

10.1016/0956-5663(96)88092-4

中图分类号：

Q6 [生物物理学];

学科分类号：

071011 ;

摘要：

The electrocatalytic oxidation of NADH was evaluated from cyclic voltammetry with heterocyclic quinones dissolved in a water solution. The process of oxidation is not sensitive to the nature of the electrode surface and takes place on platinum, glassy carbon or carbon electrodes. NADH and glucose sensors constructed were investigated and operated at 0 mV vs. Ag/AgCl (in saturated KCl) using single potential step chronoamperometry. (C) 1996 Elsevier Science Limited

引用

收藏

页码：1267 / 1275

页数：9

相关论文

共 28 条

[1] ENZYMATIC DETERMINATION OF GLUCOSE IN A FLOW SYSTEM BY CATALYTIC-OXIDATION OF THE NICOTINAMIDE COENZYME AT A MODIFIED ELECTRODE [J].

APPELQVIST, R ;

MARKOVARGA, G ;

GORTON, L ;

TORSTENSSON, A ;

JOHANSSON, G .

ANALYTICA CHIMICA ACTA, 1985, 169 (MAR) :237-247

[2] MECHANISM OF THE OXIDATION OF NADH BY QUINONES - ENERGETICS OF ONE-ELECTRON AND HYDRIDE ROUTES [J].

CARLSON, BW ;

MILLER, LL .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1985, 107 (02) :479-485

[3] FERROCENE-MEDIATED ENZYME ELECTRODE FOR AMPEROMETRIC DETERMINATION OF GLUCOSE [J].

CASS, AEG ;

DAVIS, G ;

FRANCIS, GD ;

HILL, HAO ;

ASTON, WJ ;

HIGGINS, IJ ;

PLOTKIN, EV ;

SCOTT, LDL ;

TURNER, APF .

ANALYTICAL CHEMISTRY, 1984, 56 (04) :667-671

[4] CHEMICAL-PROPERTIES OF PHENANTHROLINEQUINONES AND THE MECHANISM OF AMINE OXIDATION BY ORTHO-QUINONES OF MEDIUM REDOX POTENTIALS [J].

ECKERT, TS ;

BRUICE, TC .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1983, 105 (13) :4431-4441

[5] SOME ELECTROCHEMICAL AND CHEMICAL-PROPERTIES OF METHOXATIN AND ANALOGOUS QUINOQUINONES [J].

ECKERT, TS ;

BRUICE, TC ;

GAINOR, JA ;

WEINREB, SM .

PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA-BIOLOGICAL SCIENCES, 1982, 79 (08) :2533-2536

[6]

EVANS DH, 1982, J ELECTROANAL CHEM, V134, P301

[7] ENERGETIC COMPARISON BETWEEN PHOTOINDUCED ELECTRON-TRANSFER REACTIONS FROM NADH MODEL COMPOUNDS TO ORGANIC AND INORGANIC OXIDANTS AND HYDRIDE-TRANSFER REACTIONS FROM NADH MODEL COMPOUNDS TO PARA-BENZOQUINONE DERIVATIVES [J].

FUKUZUMI, S ;

KOUMITSU, S ;

HIRONAKA, K ;

TANAKA, T .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1987, 109 (02) :305-316

[8] NA+-CATALYZED REDUCTION OF SEMIQUINONE RADICAL-ANIONS BY NADH ANALOGS [J].

FUKUZUMI, S ;

TOKUDA, Y .

CHEMISTRY LETTERS, 1992, (08) :1497-1500

[9] CHEMICALLY MODIFIED ELECTRODES FOR THE ELECTROCATALYTIC OXIDATION OF NICOTINAMIDE COENZYMES [J].

GORTON, L .

JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS I, 1986, 82 :1245-1258

[10] ELECTROCATALYTIC OXIDATION OF REDUCED NICOTINAMIDE COENZYMES BY GRAPHITE-ELECTRODES MODIFIED WITH AN ADSORBED PHENOXAZINIUM SALT, MELDOLA BLUE [J].

GORTON, L ;

TORSTENSSON, A ;

JAEGFELDT, H ;

JOHANSSON, G .

JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1984, 161 (01) :103-120