SrNi(VO4)(OH): The High-Temperature Hydrothermal Synthesis and Magnetic Properties of an Adelite-Descloizite-Type Structure

被引：3

作者：

Sanjeewa, Liurukara D. ^{[1
,2
]}

Pellizzeri, Tiffany M. Smith ^{[3
]}

McMillen, Colin D. ^{[4
]}

Taddei, Keith ^{[5
]}

Heitmann, Thomas ^{[1
,6
]}

Kaiser, Helmut ^{[1
,6
]}

Kolis, Joseph W. ^{[4
]}

机构：

[1] Univ Missouri, Res Reactor MURR, Columbia, MO 65211 USA

[2] Univ Missouri, Dept Chem, Columbia, MO 65211 USA

[3] Eastern Illinois Univ, Dept Chem & Biochem, Charleston, IL 61920 USA

[4] Clemson Univ, Ctr Opt Mat Sci & Engn Technol COMSET, Dept Chem, Clemson, SC 29634 USA

[5] Oak Ridge Natl Lab, Neutron Scattering Div, Oak Ridge, TN 37831 USA

[6] Univ Missouri, Dept Phys & Astron, Columbia, MO 65211 USA

来源：

CRYSTALS | 2022年 / 12卷 / 10期

基金：

美国国家科学基金会;

关键词：

hydrothermal; vanadates; nickel(II); antiferomagnetism; TRANSITION; CRYSTAL; GROWTH; BRACKEBUSCHITE; CHEMISTRY; VANADATES; LATTICES; OXIDES; ROUTE; MN3+;

D O I：

10.3390/cryst12101360

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

Single crystals of a new transition metal adelite-descloizite-type structure were synthesized using a high temperature (580 degrees C) high-pressure hydrothermal technique. Single crystal X-ray diffraction and energy dispersive X-ray analysis (EDX) were used to investigate the structure and elemental composition, respectively. SrNi(VO4)(OH) crystallizes in an acentric orthorhombic crystal system in the space group P2(1)2(1)2(1) (no. 19); Z = 4, a = 5.9952(4) angstrom, b = 7.5844(4) angstrom, c = 9.2240(5) angstrom. The structure is comprised of a Ni-O-V framework where Sr2+ ions reside inside the channels. Single-crystal magnetic measurements display a significant anisotropy in both temperature- and field-dependent data. The temperature dependent magnetic measurement shows antiferromagnetic behavior at T-N similar to 8 K. Overall, the magnetic properties indicate the presence of competing antiferromagnetic and ferromagnetic interactions of SrNi(VO4)(OH).

引用

页数：11

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