Sorption of Cr(VI) ions on two Lewatit-anion exchange resins and their quantitative determination using UV-visible spectrophotometer

被引:188
作者
Pehlivan, E. [1 ]
Cetin, S. [1 ]
机构
[1] Selcuk Univ, Dept Chem Engn, TR-42031 Konya, Turkey
关键词
Anion exchange resin; Batch adsorption; Chromium; Adsorption isotherms; ATOMIC-ABSORPTION-SPECTROMETRY; WASTE-WATER; AQUEOUS-SOLUTIONS; SELECTIVE REMOVAL; TOTAL CHROMIUM; CHROMATE ION; ADSORPTION; SPECIATION; CHROMATOGRAPHY; ALIQUAT-336;
D O I
10.1016/j.jhazmat.2008.06.115
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
The sorption of Cr(VI) from aqueous solutions with macroporous resins which contain quarternary amine groups (Lewatit MP 64 and Lewatit MP 500) was studied at varying Cr(VI) concentration, adsorbent dose. pH, contact time and temperature. Batch shaking sorption experiments were carried out to evaluate the performance of Lewatit MP 64 and Lewatit MP 500 anion exchange resins in the removal of Cr(VI) from aqueous solutions. The concentration of Cr(VI) in aqueous solution was determined by UV-visible spectrophotometer. The ion exchange process, which is dependent on pH, showed maximum removal of Cr(VI) in the pH range 3-7 for an initial Cr(VI) concentration of 1 x 10(-3) M. The optimum pH for Cr(VI) adsorption was found as 5.0 for Lewatit MP 64 and 6.0 for Lewatit MP 500. The maximum Cr(VI) adsorption at pH 5.0 is 0.40 and 0.41 mmol/g resin for Lewatit MP 64 and Lewatit MP 500 anion exchangers, respectively. The maximum chromium sorption occurred at approximately 60 min for Lewatit MP 64 and 75 min for Lewatit MP 500. The suitability of the Freundlich and Langmuir adsorption models was also investigated for each chromium-sorbent system. The uptake of Cr(VI) by the anion exchange resins was reversible and so it has good potential for the removal of Cr(VI) from aqueous solutions. Both ion exchangers had high bonding constants but Lewatit MP 500 showed stronger binding. The rise in the temperature caused a slight decrease in the value of the equilibrium constant (K(c)) for the sorption of Cr(VI) ion. (c) 2008 Elsevier B.V. All rights reserved.
引用
收藏
页码:448 / 453
页数:6
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