Nickel-Catalyzed Intramolecular Coupling of Sulfones via the Extrusion of Sulfur Dioxide

被引：25
作者：
Yu, Tian-Yang [1 ]
Zheng, Zhao-Jing [2 ]
Bai, Jing-Hua [1 ]
Fang, Hong [1 ]
Wei, Hao [1 ]
机构：
[1] Northwest Univ, Coll Chem & Mat Sci, Minist Educ, Key Lab Synthet & Nat Funct Mol Chem, Xian 710127, Shaanxi, Peoples R China
[2] Lanzhou Univ, State Key Lab Appl Organ Chem, Lanzhou 730000, Gansu, Peoples R China
来源：
ADVANCED SYNTHESIS & CATALYSIS | 2019年 / 361卷 / 09期
关键词：
Desulfonylative coupling; Nickel-catalysis; Biaryl; Sulfone; C-S activation; C-C BOND; CONJUGATED YNONES; GRIGNARD-REAGENTS; DECARBONYLATION; CLEAVAGE; ACTIVATION; KETONES; DERIVATIVES; OLEFINS; ACIDS;
D O I：
10.1002/adsc.201801733
中图分类号：
O69 [应用化学];
学科分类号：
081704 ;
摘要：
We describe a method for intramolecular desulfonylative coupling using bis(cyclooctadiene) nickel as a catalyst. A broad range of aromatic, heteroaromatic and aliphatic sulfones can be utilized as substrates in this process. This method provides an atom- economical route to the synthesis of various biaryls and an efficient tool for the catalytic conversion of sulfonyl groups, representing a significant advancement in organic synthesis
引用
收藏
页码：2020 / 2024
页数：5
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