SbHPO3F: 2D van der Waals Layered Phosphite Exhibiting Large Birefringence

被引：22
|
作者：
Long, Ying [1 ]
Dong, Xuehua [2 ]
Huang, Ling [2 ]
Zeng, Hongmei [1 ]
Lin, Zhien [1 ]
Zou, Guohong [1 ]
机构：
[1] Sichuan Univ, Coll Chem, Chengdu 610065, Peoples R China
[2] Sichuan Normal Univ, Coll Chem & Mat Sci, Chengdu 610066, Peoples R China
来源：
INORGANIC CHEMISTRY | 2022年 / 61卷 / 43期
基金：
中国国家自然科学基金;
关键词：
CRYSTAL; SULFATE;
D O I：
10.1021/acs.inorgchem.2c03266
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A novel antimony(III)-based phosphite, SbHPO3F, featuring a unique two-dimensional (2D) van der Waals layered structure, has been successfully designed and synthesized via the simultaneous employment of optically active moieties including SbO3F seesaw and tetrahedral HPO3 groups. Its optimized layered arrangement formed by the alternating connection of 4-membered rings (4-MRs) and 8-MRs endows the title compound with desirable optical properties including a large birefringence and short ultraviolet (UV) cutoff edge, implying that it is a potential UV birefringent material.
引用
收藏
页码：16997 / 17001
页数：5
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