SbHPO3F: 2D van der Waals Layered Phosphite Exhibiting Large Birefringence

被引：22
|
作者：
Long, Ying [1 ]
Dong, Xuehua [2 ]
Huang, Ling [2 ]
Zeng, Hongmei [1 ]
Lin, Zhien [1 ]
Zou, Guohong [1 ]
机构：
[1] Sichuan Univ, Coll Chem, Chengdu 610065, Peoples R China
[2] Sichuan Normal Univ, Coll Chem & Mat Sci, Chengdu 610066, Peoples R China
来源：
INORGANIC CHEMISTRY | 2022年 / 61卷 / 43期
基金：
中国国家自然科学基金;
关键词：
CRYSTAL; SULFATE;
D O I：
10.1021/acs.inorgchem.2c03266
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A novel antimony(III)-based phosphite, SbHPO3F, featuring a unique two-dimensional (2D) van der Waals layered structure, has been successfully designed and synthesized via the simultaneous employment of optically active moieties including SbO3F seesaw and tetrahedral HPO3 groups. Its optimized layered arrangement formed by the alternating connection of 4-membered rings (4-MRs) and 8-MRs endows the title compound with desirable optical properties including a large birefringence and short ultraviolet (UV) cutoff edge, implying that it is a potential UV birefringent material.
引用
收藏
页码：16997 / 17001
页数：5
相关论文
共 50 条
  • [1] Van der Waals stacked 2D layered materials for optoelectronics
    Zhang, Wenjing
    Wang, Qixing
    Chen, Yu
    Wang, Zhuo
    Wee, Andrew T. S.
    2D MATERIALS, 2016, 3 (02):
  • [2] Van der Waals 2D layered-material bipolar transistor
    Aftab, Sikandar
    Eom, Jonghwa
    2D MATERIALS, 2019, 6 (03):
  • [3] van der Waals Junctions of Layered 2D Materials for Functional Devices
    Machida, Tomoki
    Moriya, Rai
    Arai, Miho
    Sata, Yohta
    Yamaguchi, Takehiro
    Yabuki, Naoto
    Morikawa, Sei
    Masubuchi, Satoru
    Ueno, Keiji
    2015 IEEE INTERNATIONAL ELECTRON DEVICES MEETING (IEDM), 2015,
  • [4] Interfacial Engineering of Van der Waals Coupled 2D Layered Materials
    Hong, Hao
    Liu, Can
    Cao, Ting
    Jin, Chenhao
    Wang, Shaoxin
    Wang, Feng
    Liu, Kaihui
    ADVANCED MATERIALS INTERFACES, 2017, 4 (09):
  • [5] Ionic Control over Ferroelectricity in 2D Layered van der Waals Capacitors
    Neumayer, Sabine M.
    Si, Mengwei
    Li, Junkang
    Liao, Pai-Ying
    Tao, Lei
    O'Hara, Andrew
    Pantelides, Sokrates T.
    Ye, Peide D.
    Maksymovych, Petro
    Balke, Nina
    ACS APPLIED MATERIALS & INTERFACES, 2022, 14 (02) : 3018 - 3026
  • [6] 2D Layered Material-Based van der Waals Heterostructures for Optoelectronics
    Zhou, Xing
    Hu, Xiaozong
    Yu, Jing
    Liu, Shiyuan
    Shu, Zhaowei
    Zhang, Qi
    Li, Huiqiao
    Ma, Ying
    Xu, Hua
    Zhai, Tianyou
    ADVANCED FUNCTIONAL MATERIALS, 2018, 28 (14)
  • [7] 2D materials and van der Waals heterostructures
    Novoselov, K. S.
    Mishchenko, A.
    Carvalho, A.
    Castro Neto, A. H.
    SCIENCE, 2016, 353 (6298)
  • [8] Generation of large strains in 2D van der Waals materials at cryogenic temperatures
    John Cenker
    Nature Reviews Physics, 2022, 4 : 631 - 631
  • [9] Generation of large strains in 2D van der Waals materials at cryogenic temperatures
    Cenker, John
    NATURE REVIEWS PHYSICS, 2022, 4 (10) : 631 - 631
  • [10] Discovery of 2D van der Waals layered MoSi2N4 family
    Novoselov, Kostya S.
    NATIONAL SCIENCE REVIEW, 2020, 7 (12) : 1842 - +
12345