An improved method for determining the external specific surface area and the plasticity index of clayey samples based on a simplified method for non-swelling fine-grained soils

被引:14
作者
Garzon, E. [1 ]
Sanchez-Soto, P. J. [2 ,3 ]
机构
[1] Univ Almeria, High Politech Coll, Dept Engn, Almeria 04120, Spain
[2] Joint Ctr Spanish Natl Res Council CSIC, Inst Mat Sci Sevilla ICMS, Seville 41092, Spain
[3] Univ Seville, Seville 41092, Spain
关键词
Specific surface area; Plasticity index; Improved method; Prediction; Clay fraction; ATTERBERG LIMITS; MINERALOGY; ADSORPTION; LINE;
D O I
10.1016/j.clay.2015.07.015
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Previous studies have used the clay content of soils for estimating the specific surface areas and different correlations have been found, including plasticity-value correlations. Based on several assumptions, Dolinar (2012) proposed a simplified method for determining the external specific surface area of non-swelling fine-grained soils. An equation relates the external specific surface area (BET-nitrogen) with percentage of clay fraction (<2 mu m), determined by hydrometer method, and plasticity index (Atterberg). In this work, based on that simplified method, the authors have developed an improved method for determining the external specific surface area of fine-grained clay samples. Instead of percentage of clay fraction, it was proposed to use the clay mineral content estimated by XRD methods. From an analysis of previous Dolinars results, the calculated and measured values of external specific surface area were studied for a group of non-swelling and fine-grained soil samples (Dolinar's samples), five non-swelling clayey samples and data samples from the literature. Additionally, an estimation of the plasticity index (Atterberg) has been also considered in this improved method. Both these methods, simplified and improved, were tested and compared using all these samples. It demonstrated the practical application of both these methods for an estimation of external specific surface area and plasticity index. However, in the present research two models were considered to determine the specific surface areas (BET and Langmuir) and the influence of several sources of errors in these predictions was discussed. The predictions were found more accurate when specific surface area from Langmuir's model is considered. It is concluded that the present research will be useful for the prediction of external specific surface area and plasticity index of non-swelling clayey materials and to dispose of theoretical practical relationships between clay mineralogy and geotechnical properties of valuable interest. (C) 2015 Elsevier B.V. All rights reserved.
引用
收藏
页码:97 / 107
页数:11
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