Tunable Plastic Films of a Crystalline Polymer by Single-Crystal-to-Single-Crystal Photopolymerization of a Diene: Self-Templating and Shock-Absorbing Two-Dimensional Hydrogen-Bonding Layers

被引：80

作者：

Garai, Mousumi ^{[1
]}

Santra, Ramkinkar ^{[1
]}

Biradha, Kumar ^{[1
]}

机构：

[1] Indian Inst Technol, Dept Chem, Kharagpur 721302, W Bengal, India

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2013年 / 52卷 / 21期

关键词：

photopolymerization; polymers; self-templating; solid-state reactions; SOLID-STATE POLYMERIZATION; TOPOCHEMICAL POLYMERIZATIONS; PHOTODIMERIZATION; MACROCYCLES; MECHANISM; MONOMERS; MODELS;

D O I：

10.1002/anie.201300690

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Film review: Two amide-containing bisolefin monomers undergo solid-state polymerization (see example) through a [2+2] reaction in a single-crystal-to- single-crystal fashion. The transformation was favored by the self-templating and shock-absorbing nature of hydrogen-bonding layers. The pyridine-containing polymers were soluble and useful for making plastic films with considerable tensile strengths. Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：5548 / 5551

页数：4

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