Langmuir-Blodgett Films of Amphiphilic Thieno[3,4-c]pyrrole-4,6-dione-Based Alternating Copolymers

被引：21

作者：

Ouattara, Mariane Perpethue ^{[1
,2
]}

Lenfant, Stephane ^{[3
]}

Vuillaume, Dominique ^{[3
]}

Pezolet, Michel ^{[1
,2
]}

Rioux-Dube, Jean-Francois ^{[1
,2
]}

Brisson, Josee ^{[1
,2
]}

Leclerc, Mario ^{[1
,2
]}

机构：

[1] Univ Laval, Dept Chem, Quebec City, PQ G1V 0A6, Canada

[2] Univ Laval, Ctr Rech Mat Avances CERMA, Quebec City, PQ G1V 0A6, Canada

[3] Univ Lille Villeneuve dAscq, F-59562 Lille, France

来源：

MACROMOLECULES | 2013年 / 46卷 / 16期

基金：

加拿大自然科学与工程研究理事会;

关键词：

FIELD-EFFECT TRANSISTORS; HIGH-PERFORMANCE; REGIOREGULAR POLY(3-HEXYLTHIOPHENE); QUANTITATIVE ORIENTATION; CONJUGATED POLYMERS; INTERFACE; SEMICONDUCTORS; HOLE;

D O I：

10.1021/ma401030m

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

The synthesis of four amphiphilic thieno[3,4-c]pyrrole-4,6-dione (TPD)-based alternating copolymers and their behavior at the air-water interface are reported. Homogeneous and stable monolayers of TPD-based copolymers were prepared. Brewster angle microscopy (BAM) was utilized to characterize the morphology and topography of these Langmuir films, UV-vis absorption spectroscopy as well as atomic force microscopy has revealed a regular transfer of some copolymers on glass substrates. It was possible to obtain homogeneous Langmuir-Blodgett films of up to 30 layers. Infrared dichroic measurements revealed an edge-on orientation. These Langmuir-Blodgett films made of conjugated polymers are therefore good candidates for organic field-effect transistors (OFETs).

引用

页码：6408 / 6418

页数：11

共 57 条

[51] Morphology and phase behavior of monolayers
Vollhardt, D
[J]. ADVANCES IN COLLOID AND INTERFACE SCIENCE, 1996, 64 : 143 - 171
[52] Organic Field-Effect Transistors based on Highly Ordered Single Polymer Fibers
Wang, Suhao
Kappl, Michael
Liebewirth, Ingo
Mueller, Maren
Kirchhoff, Katrin
Pisula, Wojciech
Muellen, Klaus
[J]. ADVANCED MATERIALS, 2012, 24 (03) : 417 - +
[53] LANGMUIR-BLODGETT MANIPULATION OF POLY(3-ALKYLTHIOPHENES)
WATANABE, I
HONG, K
RUBNER, MF
[J]. LANGMUIR, 1990, 6 (06) : 1164 - 1172
[54] Thieno[3,4-c]pyrrole-4,6-dione Containing Copolymers for High Performance Field-Effect Transistors
Wu, Qinghe
Wang, Mao
Qiao, Xiaolan
Xiong, Yu
Huang, Yangguang
Gao, Xike
Li, Hongxiang
[J]. MACROMOLECULES, 2013, 46 (10) : 3887 - 3894
[55] Langmuir-Blodgett films of regioregular poly(3-hexylthiophene) as field-effect transistors
Xu, GF
Bao, ZA
Groves, JT
[J]. LANGMUIR, 2000, 16 (04) : 1834 - 1841
[56] Ordering of conjugated polymer molecules: recent advances and perspectives
Yao, Yifan
Dong, Huanli
Hu, Wenping
[J]. POLYMER CHEMISTRY, 2013, 4 (20) : 5197 - 5205
[57] Yi Z., 2012, CHEM MATER, V24, P4618

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