α-cyclodextrin assisted self-assembly of poly(ethylene glycol)-block-poly(N-isopropylacrylamide) in aqueous media

被引：6
作者：
Yuen, Fanny
Tam, Kam Chiu [1 ]
机构：
[1] Univ Waterloo, Dept Chem Engn, Waterloo, ON N2L 3G1, Canada
来源：
JOURNAL OF APPLIED POLYMER SCIENCE | 2013年 / 127卷 / 06期
基金：
加拿大自然科学与工程研究理事会;
关键词：
cyclodextrin; block copolymers; self-assembly; inclusion complexes; atom transfer radical polymerization; HYDROPHILIC BLOCK-COPOLYMER; OXIDE) TRIBLOCK COPOLYMERS; INCLUSION COMPLEXES; DIBLOCK COPOLYMERS; LIGHT-SCATTERING; PHASE-BEHAVIOR; AGGREGATION; GLYCOL); MICELLIZATION; RELEASE;
D O I：
10.1002/app.38072
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
Poly(ethylene glycol)-block-poly(N-isopropylacrylamide) (PEG-b-PNIPAM) block copolymers were synthesized by atom transfer radical polymerization, and the a-cyclodextrin (a-CD) induced self-assembly characteristics of the system were elucidated. Below the lower critical solution temperature (LCST) of PNIPAM, CD threaded onto the PEG segments and induced micellization to form rod-shaped nanostructures comprising of a PEG/a-CD condensed phase and a PNIPAM shell. Increasing the temperature of system above the LCST caused the PNIPAM segments to collapse, which resulted in the dethreading of the CD. (c) 2012 Wiley Periodicals, Inc. J. Appl. Polym. Sci., 2013
引用
收藏
页码：4785 / 4794
页数：10
相关论文
共 59 条
  • [41] Thermodynamic and nuclear magnetic resonance study of the reactions of alpha- and beta-cyclodextrin with acids, aliphatic amines, and cyclic alcohols
    Rekharsky, MV
    Mayhew, MP
    Goldberg, RN
    Ross, PD
    Yamashoji, Y
    Inoue, Y
    [J]. JOURNAL OF PHYSICAL CHEMISTRY B, 1997, 101 (01): : 87 - 100
  • [42] Inclusion compound formation with a new columnar cyclodextrin host
    Rusa, CC
    Bullions, TA
    Fox, J
    Porbeni, FE
    Wang, XW
    Tonelli, AE
    [J]. LANGMUIR, 2002, 18 (25) : 10016 - 10023
  • [43] POLY (N-ISOPROPYLACRYLAMIDE) - EXPERIMENT, THEORY AND APPLICATION
    SCHILD, HG
    [J]. PROGRESS IN POLYMER SCIENCE, 1992, 17 (02) : 163 - 249
  • [44] Hydrogen bonded assembly of poly(acrylic acid)-block-poly(L-valine) in dilute solutions
    Sinaga, A.
    Hatton, T. A.
    Tam, K. C.
    [J]. MACROMOLECULES, 2007, 40 (25) : 9064 - 9073
  • [45] Role of methyl in the phase transition of poly(N-isopropylmethacrylamide)
    Tang, Yecang
    Ding, Yanwei
    Zhang, Guangzhao
    [J]. JOURNAL OF PHYSICAL CHEMISTRY B, 2008, 112 (29) : 8447 - 8451
  • [46] Thermosensitive micelle-forming block copolymers of poly(ethylene glycol) and poly(N-isopropylacrylamide)
    Topp, MDC
    Dijkstra, PJ
    Talsma, H
    Feijen, J
    [J]. MACROMOLECULES, 1997, 30 (26) : 8518 - 8520
  • [47] Supramolecular self-assembly through inclusion complex formation between poly(ethylene oxide-b-N-isopropylacrylamide) block copolymer and α-cyclodextrin
    Tu, Cheng-Wei
    Kuo, Shiao-Wei
    Chang, Feng-Chih
    [J]. POLYMER, 2009, 50 (13) : 2958 - 2966
  • [48] Cyclodextrin-Based Polymeric Materials: Synthesis, Properties, and Pharmaceutical/Biomedical Applications
    van de Manakker, Frank
    Vermonden, Tina
    van Nostrum, Cornelus F.
    Hennink, Wim E.
    [J]. BIOMACROMOLECULES, 2009, 10 (12) : 3157 - 3175
  • [49] Aggregation in aqueous poly(N-isopropylacrylamide)-block-poly(ethylene oxide) solutions studied by fluorescence spectroscopy and light scattering
    Virtanen, J
    Holappa, S
    Lemmetyinen, H
    Tenhu, H
    [J]. MACROMOLECULES, 2002, 35 (12) : 4763 - 4769
  • [50] Self-assembled nanoreactors
    Vriezema, DM
    Aragonès, MC
    Elemans, JAAW
    Cornelissen, JJLM
    Rowan, AE
    Nolte, RJM
    [J]. CHEMICAL REVIEWS, 2005, 105 (04) : 1445 - 1489
123456