Inductive Effects through Alkyl Groups - How Long is Long Enough?

被引：29

作者：

Tandon, Raman ^{[1
]}

Nigst, Tobias A. ^{[1
]}

Zipse, Hendrik ^{[1
]}

机构：

[1] LMU Munchen, Dept Chem, D-81377 Munich, Germany

来源：

EUROPEAN JOURNAL OF ORGANIC CHEMISTRY | 2013年 / 2013卷 / 24期

关键词：

Through-bond interactions; Reaction mechanisms; Lewis bases; Nitrogen heterocycles; Kinetics;

D O I：

10.1002/ejoc.201300486

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The influence of the length of alkyl substituents on various kinetic, thermodynamic, and spectroscopic properties of 4-(dialkylamino)pyridines has been determined by using a combination of experimental and theoretical methods. The chain-length dependence of these properties has subsequently been analyzed by using a quantitative model for through-bond inductive effects.

引用

页码：5423 / 5430

页数：8

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