A novel 2D (4,4) cobalt(II)-organic framework based on tetranuclear cluster nodes and double stranded organic linkers

被引:12
作者
Zhou, Yan [1 ]
Han, Lei [1 ]
Pan, Jianguo [1 ]
Li, Xing [1 ]
Zheng, Yueqing [1 ]
机构
[1] Ningbo Univ, Fac Chem Engn & Mat Sci, State Key Lab Base Novel Funct Mat & Preparat Sci, Ningbo 315211, Zhejiang, Peoples R China
基金
美国国家科学基金会;
关键词
Metal-organic frameworks; Cobalt(II); Tetranuclear clusters; 4,4 '-(Hexafluoroisopropylidene)bis(benzoic acid);
D O I
10.1016/j.inoche.2008.06.008
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
A novel 2D cobalt(II)-organic framework, [Co2(mu(2)-H2O)(hfipbb)(2)(py)(3)] center dot 2(py)](n) (1) (H(2)hfipbb = 4,4'-(hexafluoroisopropylidene)bis(benzoic acid), py = pyridine), has been synthesized under hydrothermal reaction. Single-crystal X-ray diffraction revealed that I is a noninterpenetration (4,4) network based on unique tetranuclear clusters and double stranded organic linkers. The powder X-ray diffraction and thermogravimetric analysis of I have also been investigated. (C) 2008 Published by Elsevier B.V.
引用
收藏
页码:1107 / 1109
页数:3
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