A novel 2D (4,4) cobalt(II)-organic framework based on tetranuclear cluster nodes and double stranded organic linkers

被引：12

作者：

Zhou, Yan ^{[1
]}

Han, Lei ^{[1
]}

Pan, Jianguo ^{[1
]}

Li, Xing ^{[1
]}

Zheng, Yueqing ^{[1
]}

机构：

[1] Ningbo Univ, Fac Chem Engn & Mat Sci, State Key Lab Base Novel Funct Mat & Preparat Sci, Ningbo 315211, Zhejiang, Peoples R China

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 2008年 / 11卷 / 10期

基金：

美国国家科学基金会;

关键词：

Metal-organic frameworks; Cobalt(II); Tetranuclear clusters; 4,4 '-(Hexafluoroisopropylidene)bis(benzoic acid);

D O I：

10.1016/j.inoche.2008.06.008

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A novel 2D cobalt(II)-organic framework, [Co2(mu(2)-H2O)(hfipbb)(2)(py)(3)] center dot 2(py)](n) (1) (H(2)hfipbb = 4,4'-(hexafluoroisopropylidene)bis(benzoic acid), py = pyridine), has been synthesized under hydrothermal reaction. Single-crystal X-ray diffraction revealed that I is a noninterpenetration (4,4) network based on unique tetranuclear clusters and double stranded organic linkers. The powder X-ray diffraction and thermogravimetric analysis of I have also been investigated. (C) 2008 Published by Elsevier B.V.

引用

收藏

页码：1107 / 1109

页数：3

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