The synthesis and crystal structure of the first metal-bound stannatrane complex Os(Sn[OCH2CH2]3N)(η2-S2CNMe2)(CO)(PPh3)2:: structural comparisons with the analogous silatrane complex Os(Si[OCH2CH2]3N)(η2-S2CNMe2)(CO)(PPh3)2

被引：42
|
作者：
Rickard, CEF [1 ]
Roper, WR [1 ]
Woodman, TJ [1 ]
Wright, LJ [1 ]
机构：
[1] Univ Auckland, Dept Chem, Auckland, New Zealand
来源：
CHEMICAL COMMUNICATIONS | 1999年 / 09期
关键词：
D O I：
10.1039/a901408j
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The first metal substituted stannatrane,Os(Sn-[OCH2CH2](3)N)(eta(2)-S2CNMe2)(CO)(PPh3)(2), has been synthesised by reaction between triethanolamine and the triiodostannyl osmium complex Os(SnI3)(eta(2)-S2CNMe2)-(CO)(PPh3)(2): the transannular Sn-N distance of 2.422(4) Angstrom indicates a bonding interaction which is not seen in the corresponding silatranyl complex Os(Si[OCH2CH2](3)N)(eta(2)-S2CNMe2)(CO)(PPh3)(2) which has an Si-N distance of 3.176(6) Angstrom.
引用
收藏
页码：837 / 838
页数：2
相关论文
共 50 条
  • [21] Silicon-carbon bond cleavage of organosilicon amines MenN[CH2Si(OCH2CH2)3N]3-n (n=1, 2) by phenols
    Lazareva, NF
    Brodskaya, EI
    Ratovsky, GV
    JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2, 2002, (12): : 2083 - 2086
  • [22] Syntheses and reactions of the carbyne complexes, M(CR)Cl(CO)(PPh3)2 (M = Ru, Os; R = 1-naphthyl, 2-naphthyl).: The crystal structures of [Os(C-1-naphthyl)(CO)2(PPh3)2]ClO4, Os(=CH-2-naphthyl)Cl2(CO)(PPh3)2, and Os(2-naphthyl)Cl(CO)2(PPh3)2
    Baker, LJ
    Clark, GR
    Rickard, CEF
    Roper, WR
    Woodgate, SD
    Wright, LJ
    JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1998, 551 (1-2) : 247 - 259
  • [23] STRUCTURE OF 1-METHYLSILATRANONE, CH3SI(OCOCH2)(OCH2CH2)2N
    FULOP, V
    KALMAN, A
    HENCSEI, P
    CSONKA, G
    KOVACS, I
    ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1988, 44 : 720 - 723
  • [24] Preparation and crystal structures of Ag[N(CN)2](PPh3)2, Cu[N(CN)2](PPh3)2, and Ag[N(CN)2](PPh3)3
    Bessler, KE
    Romualdo, LL
    Deflon, VM
    Hagenbach, A
    ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 2000, 626 (09): : 1942 - 1945
  • [25] Preparation and characterisation of N(CH(2)PPh(2))(3), N(CH(2)PPh(2))(3)Mo(CO)(3) and [HN(CH(2)PPh(2))(3)Mo(CO)(3)]BF4
    Walter, O
    Huttner, G
    Kern, R
    ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 1996, 51 (07): : 922 - 928
  • [26] Synthesis and Crystal Structure of Complex (μ-S2)Fe2(CO)4(PPh3)2
    Gao, Wei
    Yang, Juan Yuan Jing
    ASIAN JOURNAL OF CHEMISTRY, 2013, 25 (17) : 9755 - 9757
  • [27] TRIMETHYLAMINE OXIDE INDUCED DECARBONYLATION OF RU(CO)2CL-2(PPH3)2, OS(CO)2CL-2(PPH3)2 COMPLEXES
    FOLEY, BL
    SMITH, CA
    THOMAS, NC
    INORGANICA CHIMICA ACTA, 1988, 150 (02) : 163 - 163
  • [28] THE CYCLIC AMINOPHOSPHANE LIGAND PHP(OCH2CH2)2NH IN IRON NITROSYL COMPLEXES - CRYSTAL AND MOLECULAR-STRUCTURES OF FE(NO)2(PHP(OCH2CH2)2NH)2 AND FE(NO)2(PHP(OCH2CH2)2N(H)BPH3)2
    LEBORGNE, G
    MORDENTI, L
    RIESS, JG
    ROUSTAN, JL
    NOUVEAU JOURNAL DE CHIMIE-NEW JOURNAL OF CHEMISTRY, 1986, 10 (02): : 97 - 106
  • [29] Structure of the [Co(NioxH)2(PPh3)2]F complex
    Malinovsky, ST
    Coropcheanu, EB
    Zavodnik, VE
    Bologa, OA
    CRYSTALLOGRAPHY REPORTS, 2002, 47 (01) : 51 - 54
  • [30] Structure of the [Co(NioxH)2(PPh3)2]F complex
    Malinovskij, S.T.
    Coropcheanu, E.B.
    Zavodnik, V.E.
    Bologa, O.A.
    Kristallografiya, 2002, 47 (01): : 58 - 62
12345