Double-quantum 13C nuclear magnetic resonance of bathorhodopsin, the first photointermediate in mammalian vision

被引：38

作者：

Concistre, Maria ^{[1
]}

Gansmuller, Axel ^{[1
]}

McLean, Neville ^{[1
]}

Johannessen, Ole G. ^{[1
]}

Montesinos, Ildefonso Marin ^{[1
]}

Bovee-Geurts, Petra H. M. ^{[3
]}

Verdegem, Peter ^{[2
]}

Lugtenburg, Johan ^{[2
]}

Brown, Richard C. D. ^{[1
]}

DeGrip, Willem J. ^{[3
]}

Levitt, Malcolm H. ^{[1
]}

机构：

[1] Univ Southampton, Sch Chem, Southampton SO17 1BJ, Hants, England

[2] Leiden Univ, Leiden Inst Chem, Gorlaeus Labs, NL-2300 RA Leiden, Netherlands

[3] Radboud Univ Nijmegen, Nijmegen Ctr Mol Life Sci, NL-6500 HB Nijmegen, Netherlands

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2008年 / 130卷 / 32期

基金：

英国生物技术与生命科学研究理事会;

关键词：

D O I：

10.1021/ja803801u

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The C-13 chemical shifts of the primary visual photointermediate bathorhodopsin have been observed by performing double-quantum magic-angle-spinning NMR at low temperature in the presence of illumination. Strong isomerization shifts have been observed upon the conversion of rhodopsin into bathorhodopsin.

引用

页码：10490 / +

页数：3

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