Investigation of Cr3+ ions in Cs2NaGaF6 single crystals by optical spectroscopy

被引：50
作者：
da Fonseca, RJM
Tavares, AD
Silva, PS
Abritta, T
Khaidukov, NM
机构：
[1] UERJ, Inst Fis, BR-20550013 Rio De Janeiro, Brazil
[2] UFRJ, Inst Fis, BR-21945970 Rio De Janeiro, Brazil
[3] Russian Acad Sci, Inst Gen & Inorgan Chem, Moscow 117907, Russia
来源：
SOLID STATE COMMUNICATIONS | 1999年 / 110卷 / 09期
关键词：
insulators; crystal and ligand fields; optical properties; luminescence; time-resolved optical spectroscopy;
D O I：
10.1016/S0038-1098(99)00008-3
中图分类号：
O469 [凝聚态物理学];
学科分类号：
070205 ;
摘要：
Two different Cr3+ crystal-field sites in the elpasolite Cs2NaGaF6 were investigated by excitation and emission spectroscopy at 4.2, 77 and 300 K. The zero-phonon lines of the E-2 --> (4)A(2) transition are clearly observed on time-resolved emission spectra and associated with each type of site by high-resolution emission measurements. The different fluorescence lifetimes at 4.2 K confirm the identification of the sites. The crystal-field parameter, Dq, and Racah parameters, B and C, are determined, and we establish an intermediate crystal-field situation for both Cr3+ centers. (C) 1999 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码：519 / 524
页数：6
相关论文
共 50 条
[21]   High pressure optical studies of α-ZnAl2S4:Cr3+ [J].
Jovanic, B. R. ;
Broussell, I. ;
Panic, B. ;
Radenkovic, B. ;
Despotovic, M. .
MATERIALS RESEARCH BULLETIN, 2010, 45 (02) :186-189
[22]   Tuning ferromagnetism in zinc oxide nanoparticles by replacing Zn2+ ions ions with Cr3+ ions ions [J].
Guruvammal, D. ;
Selvaraj, S. ;
Sundar, S. Meenakshi .
EUROPEAN PHYSICAL JOURNAL PLUS, 2018, 133 (09)
[23]   EPR and optical absorption studies of Cr3+ ions in D-gluconic acid monohydrate [J].
Kripal, Ram ;
Singh, Pragya ;
Govind, Har .
SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY, 2009, 74 (02) :357-362
[24]   Electron paramagnetic resonance and optical absorption spectra of Cr3+ ions in cadmium phosphate glass [J].
Ravikumar, RVSSN ;
Komatsu, R ;
Ikeda, K ;
Chandrasekhar, AV ;
Reddy, BJ ;
Reddy, YP ;
Rao, PS .
SOLID STATE COMMUNICATIONS, 2003, 126 (05) :251-253
[25]   Optical and structural properties of nanosized ZnGa2O4:Cr3+ phosphor [J].
Kim, JS ;
Kim, JS ;
Park, HL .
SOLID STATE COMMUNICATIONS, 2004, 131 (12) :735-738
[26]   Structural and optical properties of crystalline and nanocrystalline NaIn(WO4)2:Cr3+ [J].
Fuks, H. ;
Skibinski, T. ;
Kaczmarek, S. M. ;
Hanuza, J. ;
Leniec, G. ;
Hermanowicz, K. ;
Maczka, M. ;
Ptak, M. .
JOURNAL OF ALLOYS AND COMPOUNDS, 2014, 585 :722-728
[27]   Optical properties of Cr3+:NaAl(WO4)2 crystals, a new candidate for broadband laser applications [J].
Nikolov, I ;
Mateos, X ;
Güell, F ;
Massons, J ;
Nikolov, V ;
Peshev, P ;
Díaz, F .
OPTICAL MATERIALS, 2004, 25 (01) :53-58
[28]   Optical spectra and energy levels of the Cr3+ ions in MWO4 (M = Mg, Zn, Cd) and MgMoO4 crystals [J].
Cavalli, E. ;
Belletti, A. ;
Brik, M. G. .
JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS, 2008, 69 (01) :29-34
[29]   Combustion synthesis and nontrivial luminescence properties of nanosized δ*-Al2O3 doped with Cr3+ ions [J].
Dotsenko, Vladimir P. ;
Berezovskaya, Irina, V ;
Poletaev, Nikolay, I ;
Khlebnikova, Maria E. ;
Zatovsky, Igor, V ;
Bychkov, Konstantin L. ;
Khomenko, Olena, V ;
Efryushina, Ninel P. .
SOLID STATE SCIENCES, 2021, 119
[30]   Single crystal EPR, optical absorption and superposition model study of Cr3+ doped ammonium dihydrogen phosphate [J].
Kripal, Ram ;
Pandey, Sangita .
SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY, 2010, 76 (01) :62-70
12345